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In chemistry, IUPAC changed its definition of standard temperature and pressure in 1982: [1] [2] Until 1982, STP was defined as a temperature of 273.15 K (0 °C, 32 °F) and an absolute pressure of exactly 1 atm (101.325 kPa).
The standard molar entropy of a gas at STP includes contributions from: [2] The heat capacity of one mole of the solid from 0 K to the melting point (including heat absorbed in any changes between different crystal structures). The latent heat of fusion of the solid. The heat capacity of the liquid from the melting point to the boiling point.
The standard state should not be confused with standard temperature and pressure (STP) for gases, [4] nor with the standard solutions used in analytical chemistry. [5] STP is commonly used for calculations involving gases that approximate an ideal gas, whereas standard state conditions are used for thermodynamic calculations. [6]
For many substances, the formation reaction may be considered as the sum of a number of simpler reactions, either real or fictitious. The enthalpy of reaction can then be analyzed by applying Hess' law, which states that the sum of the enthalpy changes for a number of individual reaction steps equals the enthalpy change of the overall reaction.
Isotherms of an ideal gas for different temperatures. The curved lines are rectangular hyperbolae of the form y = a/x. They represent the relationship between pressure (on the vertical axis) and volume (on the horizontal axis) for an ideal gas at different temperatures: lines that are farther away from the origin (that is, lines that are nearer to the top right-hand corner of the diagram ...
Sodium triphosphate (STP), also sodium tripolyphosphate (STPP), or tripolyphosphate (TPP), [1]) is an inorganic compound with formula Na 5 P 3 O 10. It is the sodium salt of the polyphosphate penta-anion, which is the conjugate base of triphosphoric acid. It is produced on a large scale as a component of many domestic and industrial products ...
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In thermodynamics, the enthalpy of sublimation, or heat of sublimation, is the heat required to sublimate (change from solid to gas) one mole of a substance at a given combination of temperature and pressure, usually standard temperature and pressure (STP). It is equal to the cohesive energy of the solid.