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The Tetens equation is an equation to calculate the saturation vapour pressure of water over liquid and ice. It is named after its creator, O. Tetens who was an early German meteorologist. It is named after its creator, O. Tetens who was an early German meteorologist.
In the case of an equilibrium solid, such as a crystal, this can be defined as the pressure when the rate of sublimation of a solid matches the rate of deposition of its vapor phase. For most solids this pressure is very low, but some notable exceptions are naphthalene , dry ice (the vapor pressure of dry ice is 5.73 MPa (831 psi, 56.5 atm) at ...
The Köhler curve is the visual representation of the Köhler equation. It shows the saturation ratio – or the supersaturation = % – at which the droplet is in equilibrium with the environment over a range of droplet diameters. The exact shape of the curve is dependent upon the amount and composition of the solutes present in the atmosphere.
The saturation vapor pressure is the pressure at which water vapor is in thermodynamic equilibrium with its condensed state. At pressures higher than saturation vapor pressure, water will condense , while at lower pressures it will evaporate or sublimate .
In technical terms, the dew point is the temperature at which the water vapor in a sample of air at constant barometric pressure condenses into liquid water at the same rate at which it evaporates. [7] At temperatures below the dew point, the rate of condensation will be greater than that of evaporation, forming more liquid water.
Another type of binary phase diagram is a boiling-point diagram for a mixture of two components, i. e. chemical compounds. For two particular volatile components at a certain pressure such as atmospheric pressure , a boiling-point diagram shows what vapor (gas) compositions are in equilibrium with given liquid compositions depending on temperature.
The definition of a w is where p is the partial water vapor pressure in equilibrium with the solution, and p* is the (partial) vapor pressure of pure water at the same temperature. An alternate definition can be a w ≡ l w x w {\displaystyle a_{w}\equiv l_{w}x_{w}} where l w is the activity coefficient of water and x w is the mole fraction of ...
Ice, water, and water vapour can coexist at the triple point, which is exactly 273.16 K (0.01 °C) at a pressure of 611.657 Pa. [14] [15] The kelvin was defined as 1 / 273.16 of the difference between this triple point and absolute zero, [16] though this definition changed in May 2019. [17] Unlike most other solids, ice is difficult to ...