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  2. Reaction rate constant - Wikipedia

    en.wikipedia.org/wiki/Reaction_rate_constant

    where A and B are reactants C is a product a, b, and c are stoichiometric coefficients,. the reaction rate is often found to have the form: = [] [] Here ⁠ ⁠ is the reaction rate constant that depends on temperature, and [A] and [B] are the molar concentrations of substances A and B in moles per unit volume of solution, assuming the reaction is taking place throughout the volume of the ...

  3. Rate-determining step - Wikipedia

    en.wikipedia.org/wiki/Rate-determining_step

    In chemical kinetics, the overall rate of a reaction is often approximately determined by the slowest step, known as the rate-determining step (RDS or RD-step [1] or r/d step [2] [3]) or rate-limiting step. For a given reaction mechanism, the prediction of the corresponding rate equation (for comparison with the experimental rate law) is often ...

  4. Rate equation - Wikipedia

    en.wikipedia.org/wiki/Rate_equation

    The rate of the overall reaction depends on the slowest step, so the overall reaction will be first order when the reaction of the energized reactant is slower than the collision step. The half-life is independent of the starting concentration and is given by t 1 / 2 = ln ⁡ ( 2 ) k {\textstyle t_{1/2}={\frac {\ln {(2)}}{k}}} .

  5. Reaction rate - Wikipedia

    en.wikipedia.org/wiki/Reaction_rate

    Iron rusting has a low reaction rate. This process is slow. Wood combustion has a high reaction rate. This process is fast. The reaction rate or rate of reaction is the speed at which a chemical reaction takes place, defined as proportional to the increase in the concentration of a product per unit time and to the decrease in the concentration of a reactant per unit time. [1]

  6. Chemical kinetics - Wikipedia

    en.wikipedia.org/wiki/Chemical_kinetics

    Chemical kinetics, also known as reaction kinetics, is the branch of physical chemistry that is concerned with understanding the rates of chemical reactions. It is different from chemical thermodynamics, which deals with the direction in which a reaction occurs but in itself tells nothing about its rate.

  7. Law of mass action - Wikipedia

    en.wikipedia.org/wiki/Law_of_mass_action

    The rate of predation upon the prey is assumed to be proportional to the rate at which the predators and the prey meet; this rate is evaluated as xy, where x is the number of prey, y is the number of predator. This is a typical example of the law of mass action.

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  9. Arrhenius equation - Wikipedia

    en.wikipedia.org/wiki/Arrhenius_equation

    In physical chemistry, the Arrhenius equation is a formula for the temperature dependence of reaction rates.The equation was proposed by Svante Arrhenius in 1889, based on the work of Dutch chemist Jacobus Henricus van 't Hoff who had noted in 1884 that the Van 't Hoff equation for the temperature dependence of equilibrium constants suggests such a formula for the rates of both forward and ...