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WAO is a liquid phase reaction using dissolved oxygen in water to oxidize wastewater contaminants. The dissolved oxygen is typically supplied using pressurized air, but pure oxygen can also be used. The oxidation reaction generally occurs at moderate temperatures of 150°-320 °C and at pressures from 10 to 220 bar.
Efficient and economical water splitting would be a technological breakthrough that could underpin a hydrogen economy. A version of water splitting occurs in photosynthesis, but hydrogen is not produced. The reverse of water splitting is the basis of the hydrogen fuel cell. Water splitting using solar radiation has not been commercialized.
Since hydrogen can be used as an alternative clean burning fuel, there has been a need to split water efficiently. However, there are known materials that can mediate the reduction step efficiently therefore much of the current research is aimed at the oxidation half reaction also known as the Oxygen Evolution Reaction (OER).
Efficiency of modern hydrogen generators is measured by energy consumed per standard volume of hydrogen (MJ/m 3), assuming standard temperature and pressure of the H 2. The lower the energy used by a generator, the higher its efficiency would be; a 100%-efficient electrolyser would consume 39.4 kilowatt-hours per kilogram (142 MJ/kg) (higher ...
Oxidizing acids, being strong oxidizing agents, can often oxidize certain less reactive metals, in which the active oxidizing agent is not H + ions. For example, copper is a rather unreactive metal, and has no reaction with concentrated hydrochloric acid.
In aqueous solutions, redox potential is a measure of the tendency of the solution to either gain or lose electrons in a reaction. A solution with a higher (more positive) reduction potential than some other molecule will have a tendency to gain electrons from this molecule (i.e. to be reduced by oxidizing this other molecule) and a solution with a lower (more negative) reduction potential ...
There is no interest in generating oxygen by water oxidation since oxygen is readily obtained from air. Instead, interest in water oxidation is motivated by its relevance to water splitting, which would provide "solar hydrogen," i.e. water oxidation would generate the electrons and protons for the production of hydrogen. [2]
The half reaction, balanced with acid, is: 2 H + + 2e − → H 2. At the positively charged anode, an oxidation reaction occurs, generating oxygen gas and releasing electrons to the anode to complete the circuit: 2 H 2 O → O 2 + 4 H + + 4e −. Combining either half reaction pair yields the same overall decomposition of water into oxygen and ...