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Atmospheric pollutant concentrations expressed as mass per unit volume of atmospheric air (e.g., mg/m 3, μg/m 3, etc.) at sea level will decrease with increasing altitude because the atmospheric pressure decreases with increasing altitude. The change of atmospheric pressure with altitude can be obtained from this equation: [2]
The gram (10 −3 kg) is an SI derived unit of mass. However, the names of all SI mass units are based on gram, rather than on kilogram; thus 10 3 kg is a megagram (10 6 g), not a *kilokilogram. The tonne (t) is an SI-compatible unit of mass equal to a megagram (Mg), or 10 3 kg.
mg/m 3 = milligrams of pollutant per cubic meter of air at sea level atmospheric pressure and T: ppmv = air pollutant concentration, in parts per million by volume T = ambient temperature in K = 273. + °C 0.082057338 = Universal gas constant in L atm mol −1 K −1: M = molecular mass (or molecular weight) of the air pollutant
= molar mass of Earth's air: 0.0289644 kg/mol The value of subscript b ranges from 0 to 6 in accordance with each of seven successive layers of the atmosphere shown in the table below. The reference value for ρ b for b = 0 is the defined sea level value, ρ 0 = 1.2250 kg/m 3 or 0.0023768908 slug/ft 3 .
The values for most of the conversion factors used by Template:Convert come from international and national standards documents: . Organisation Intergouvernementale de la Convention du Mètre (2014) [2006].
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This improper name persists, especially in elementary textbooks. In biology, the unit "%" is sometimes (incorrectly) used to denote mass concentration, also called mass/volume percentage. A solution with 1 g of solute dissolved in a final volume of 100 mL of solution would be labeled as "1%" or "1% m/v" (mass/volume). This is incorrect because ...
For example, the conversion factor between a mass fraction of 1 ppb and a mole fraction of 1 ppb is about 4.7 for the greenhouse gas CFC-11 in air (Molar mass of CFC-11 / Mean molar mass of air = 137.368 / 28.97 = 4.74). For volume fraction, the suffix "V" or "v" is sometimes appended to the parts-per notation (e.g. ppmV, ppbv, pptv).