Search results
Results from the WOW.Com Content Network
It has the formula [(CH 3) 4 C 2 O 2 B] 2; the pinacol groups are sometimes abbreviated as "pin", so the structure is sometimes represented as B 2 pin 2. It is a colourless solid that is soluble in organic solvents. It is a commercially available reagent for making pinacol boronic esters for organic synthesis.
Examples of boronic esters Boronic ester Diol Structural formula Molar mass CAS number Boiling point (°C) Allylboronic acid pinacol ester: pinacol: 168.04: 72824-04-5: 50–53 (5 mmHg) Phenyl boronic acid trimethylene glycol ester: trimethylene glycol: 161.99: 4406-77-3: 106 (2 mm Hg) Diisopropoxymethylborane: isopropanol: 144.02 86595-27-9: ...
Pinacol is a branched alcohol which finds use in organic syntheses. It is a diol that has hydroxyl groups on vicinal carbon atoms. A white solid that melts just above room temperature, pinacol is notable for undergoing the pinacol rearrangement in the presence of acid and for being the namesake of the pinacol coupling reaction .
Compounds of the type BR n (OR) 3-n are called borinic esters (n = 2), boronic esters (n = 1), and borates (n = 0). Boronic acids are key to the Suzuki reaction. Trimethyl borate, debatably not an organoboron compound, is an intermediate in sodium borohydride production.
The boron atom of a boronic ester or acid is sp 2 hybridized possessing a vacant p orbital, enabling these groups to act as Lewis acids. The C–B bond of boronic acids and esters are slightly longer than typical C–C single bonds with a range of 1.55-1.59 Å.
1,2-Dichlorobenzene or ortho-dichlorobenzene; 1,3-Dichlorobenzene or meta-dichlorobenzene; 1,4-Dichlorobenzene or para-dichlorobenzene. All three isomers are colorless chlorobenzenes with the formula C 6 H 4 Cl 2. They differ structurally based on where the two chlorine atoms are attached to the ring.
2,4-Dichlorobenzoic acid is an organic compound with the formula C 6 H 3 Cl 2 CO 2 H. It is one of more important of several isomers of dichlorobenzoic acid. It can be prepared by oxidation of 2,4-dichlorotoluene. [2] The coenzyme A thioester of 2,4-dichlorobenzoic acid is the substrate for 2,4-dichlorobenzoyl reductase.
Pinacol boronic ester. Add languages. Add links. Article; Talk; English. ... Boronic acid; Retrieved from " ... Text is available under the Creative Commons ...