Search results
Results from the WOW.Com Content Network
Nickel forms double salts with Tutton's salt structure with tetrafluoroberyllate with the range of cations of ammonia, [4] potassium, rubidium, cesium, [5] and thallium. [ 6 ] Anhydrous salts of the formula M 2 Ni 2 (SO 4 ) 3 , which can be termed metal nickel trisulfates, belong to the family of langbeinites .
Nickel ions can act as a cation in salts with many acids, including common oxoacids. Salts of the hexaaqua ion (Ni · 6 H 2 O 2+) are especially well known. Many double salts containing nickel with another cation are known. There are organic acid salts. Nickel can be part of a negatively charged ion (anion) making what is called a nickellate.
The first periodatonickalates discovered were sodium nickel periodate (NaNiIO 6 ·0.5H 2 O) and potassium nickel periodate (KNiIO 6 ·0.5H 2 O). P. Ray and B. Sarma obtained these dark purple double salts in 1949, mixing nickel sulfate with potassium or sodium periodate and (as oxidant) a boiling aqueous solution of an alkali persulfate ...
Nickel acetate exists as an intermediate and the final result is that solid nickel, nickel oxide, Ni 3 C and carbon remain. [9] With malonate nickel can form a bis-malonato-nickelate anion, which can form double salts. [10] Nickel maleate can be made from maleic acid and nickel carbonate in boiling water.
The oxalatonickelates are a class of compounds that contain nickel complexed by oxalate groups. They form a series of double salts, and include clusters with multiple nickel atoms. Since oxalate functions as a bidentate ligand it can satisfy two coordinate positions around the nickel atom, or it can bridge two nickel atoms together.
The hexafluoronickelate(IV) 2− ion NiF 6 2− contains nickel in the maximal +4 state, and is in octahedral coordination by the fluoride atoms. It forms a commercially available salt Potassium hexafluoronickelate(IV) K 2 NiF 6. Solid double salts can also contain tetrafluoronickelate NiF 4 eg K 2 NiF 4.
Other examples include the vanadous Tutton salt (NH 4) 2 V(SO 4) 2 (H 2 O) 6 and the chromous Tutton salt (NH 4) 2 Cr(SO 4) 2 (H 2 O) 6. [5] In solids and solutions, the M' 2+ ion exists as a metal aquo complex [M'(H 2 O) 6] 2+. Related to the Tutton's salts are the alums, which are also double salts but with the formula MM'(SO 4) 2 (H 2 O) 12 ...
Nickel forms a series of mixed oxide compounds which are commonly called nickelates. A nickelate is an anion containing nickel or a salt containing a nickelate anion, or a double compound containing nickel bound to oxygen and other elements. Nickel can be in different or even mixed oxidation states, ranging from +1, +2, +3 to +4.