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In chemistry, a dynamic equilibrium exists once a reversible reaction occurs. Substances transition between the reactants and products at equal rates, meaning there is no net change. Reactants and products are formed at such a rate that the concentration of neither changes. It is a particular example of a system in a steady state.
D'Alembert's form of the principle of virtual work states that a system of rigid bodies is in dynamic equilibrium when the virtual work of the sum of the applied forces and the inertial forces is zero for any virtual displacement of the system. Thus, dynamic equilibrium of a system of rigid bodies with generalized coordinates requires ...
D'Alembert's form of the principle of virtual work states that a system of rigid bodies is in dynamic equilibrium when the virtual work of the sum of the applied forces and the inertial forces is zero for any virtual displacement of the system. Thus, dynamic equilibrium of a system of n rigid bodies with m generalized coordinates requires that ...
Le Châtelier's principle (1884) predicts the behavior of an equilibrium system when changes to its reaction conditions occur. If a dynamic equilibrium is disturbed by changing the conditions, the position of equilibrium moves to partially reverse the change. For example, adding more S (to the chemical reaction above) from the outside will ...
Linear dynamical systems can be solved exactly, in contrast to most nonlinear ones. Occasionally, a nonlinear system can be solved exactly by a change of variables to a linear system. Moreover, the solutions of (almost) any nonlinear system can be well-approximated by an equivalent linear system near its fixed points. Hence, understanding ...
The magnitude of the equilibrium constant depends on the Gibbs free energy change for the reaction. [2] So, when the free energy change is large (more than about 30 kJ mol −1), the equilibrium constant is large (log K > 3) and the concentrations of the reactants at equilibrium are very small. Such a reaction is sometimes considered to be an ...
A real dynamical system, real-time dynamical system, continuous time dynamical system, or flow is a tuple (T, M, Φ) with T an open interval in the real numbers R, M a manifold locally diffeomorphic to a Banach space, and Φ a continuous function. If Φ is continuously differentiable we say the system is a differentiable dynamical system.
In chemistry, a steady state is a more general situation than dynamic equilibrium. While a dynamic equilibrium occurs when two or more reversible processes occur at the same rate, and such a system can be said to be in a steady state, a system that is in a steady state may not necessarily be in a state of dynamic equilibrium, because some of ...