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Henderson–Hasselbalch equation. In chemistry and biochemistry, the Henderson–Hasselbalch equation relates the pH of a chemical solution of a weak acid to the numerical value of the acid dissociation constant, Ka, of acid and the ratio of the concentrations, of the acid and its conjugate base in an equilibrium. [1]
pH values can be measured in non-aqueous solutions, but they are based on a different scale from aqueous pH values, because the standard states used for calculating hydrogen ion concentrations are different. The hydrogen ion activity, a H +, is defined [21] [22] as:
Non-nucleophilic. Weak. v. t. e. In chemistry, an acid dissociation constant (also known as acidity constant, or acid-ionization constant; denoted ) is a quantitative measure of the strength of an acid in solution. It is the equilibrium constant for a chemical reaction. known as dissociation in the context of acid–base reactions.
The Hammett acidity function (H 0) is a measure of acidity that is used for very concentrated solutions of strong acids, including superacids.It was proposed by the physical organic chemist Louis Plack Hammett [1] [2] and is the best-known acidity function used to extend the measure of Brønsted–Lowry acidity beyond the dilute aqueous solutions for which the pH scale is useful.
Non-nucleophilic. Weak. v. t. e. An acidity function is a measure of the acidity of a medium or solvent system, [ 1][ 2] usually expressed in terms of its ability to donate protons to (or accept protons from) a solute ( Brønsted acidity ). The pH scale is by far the most commonly used acidity function, and is ideal for dilute aqueous solutions.
Acid strength is the tendency of an acid, symbolised by the chemical formula , to dissociate into a proton, , and an anion, . The dissociation or ionization of a strong acid in solution is effectively complete, except in its most concentrated solutions. Examples of strong acids are hydrochloric acid , perchloric acid , nitric acid and sulfuric ...
An elementary pH meter that can be used to monitor titration reactions. pH meter: A potentiometer with an electrode whose potential depends on the amount of H + ion present in the solution. (This is an example of an ion-selective electrode.) The pH of the solution is measured throughout the titration, more accurately than with an indicator; at ...
A buffer solution is a solution where the pH does not change significantly on dilution or if an acid or base is added at constant temperature. [1] Its pH changes very little when a small amount of strong acid or base is added to it. Buffer solutions are used as a means of keeping pH at a nearly constant value in a wide variety of chemical ...
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