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Calcium sulfate (or calcium sulphate) is the inorganic compound with the formula CaSO 4 and related hydrates. In the form of γ- anhydrite (the anhydrous form), it is used as a desiccant . One particular hydrate is better known as plaster of Paris , and another occurs naturally as the mineral gypsum .
The following chart shows the solubility of various ionic compounds in water at 1 atm pressure and room temperature (approx. 25 °C, 298.15 K). "Soluble" means the ionic compound doesn't precipitate, while "slightly soluble" and "insoluble" mean that a solid will precipitate; "slightly soluble" compounds like calcium sulfate may require heat to precipitate.
Anhydrite is 1–3% of the minerals in salt domes and is generally left as a cap at the top of the salt when the halite is removed by pore waters. The typical cap rock is a salt, topped by a layer of anhydrite, topped by patches of gypsum, topped by a layer of calcite. [ 8 ]
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Gypsum is a soft sulfate mineral composed of calcium sulfate dihydrate, with the chemical formula CaSO 4 ·2H 2 O. [4] It is widely mined and is used as a fertilizer and as the main constituent in many forms of plaster, drywall and blackboard or sidewalk chalk.
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Phosphogypsum is a by-product from the production of phosphoric acid by treating phosphate ore with sulfuric acid according to the following reaction: . Ca 5 (PO 4) 3 X + 5 H 2 SO 4 + 10 H 2 O → 3 H 3 PO 4 + 5 (CaSO 4 · 2 H 2 O) + HX