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The boiling point of water is the temperature at which the saturated vapor pressure equals the ambient pressure. Water supercooled below its normal freezing point has a higher vapor pressure than that of ice at the same temperature and is, thus, unstable. Calculations of the (saturation) vapor pressure of water are commonly used in meteorology.
There are a number of methods for calculating the sublimation pressure (i.e., the vapor pressure) of a solid. One method is to estimate the sublimation pressure from extrapolated liquid vapor pressures (of the supercooled liquid), if the heat of fusion is known, by using this particular form of the Clausius–Clapeyron relation: [ 9 ]
Torr; Other units of pressure include: The bar (symbol: bar), defined as 100 kPa exactly. The atmosphere (symbol: atm), defined as 101.325 kPa exactly. These four pressure units are used in different settings. For example, the bar is used in meteorology to report atmospheric pressures. [7] The torr is used in high-vacuum physics and engineering ...
The Antoine equation is a class of semi-empirical correlations describing the relation between vapor pressure and temperature for pure substances. The Antoine equation is derived from the Clausius–Clapeyron relation. The equation was presented in 1888 by the French engineer Louis Charles Antoine (1825–1897). [1]
The Clausius–Clapeyron equation [8]: 509 applies to vaporization of liquids where vapor follows ideal gas law using the ideal gas constant and liquid volume is neglected as being much smaller than vapor volume V. It is often used to calculate vapor pressure of a liquid. [9]
Raoult's law (/ ˈ r ɑː uː l z / law) is a relation of physical chemistry, with implications in thermodynamics.Proposed by French chemist François-Marie Raoult in 1887, [1] [2] it states that the partial pressure of each component of an ideal mixture of liquids is equal to the vapor pressure of the pure component (liquid or solid) multiplied by its mole fraction in the mixture.
Isotherms of an ideal gas for different temperatures. The curved lines are rectangular hyperbolae of the form y = a/x. They represent the relationship between pressure (on the vertical axis) and volume (on the horizontal axis) for an ideal gas at different temperatures: lines that are farther away from the origin (that is, lines that are nearer to the top right-hand corner of the diagram ...
The Tetens equation is an equation to calculate the saturation vapour pressure of water over liquid and ice. It is named after its creator, O. Tetens who was an early German meteorologist. It is named after its creator, O. Tetens who was an early German meteorologist.