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Ammonia solution, also known as ammonia water, ammonium hydroxide, ammoniacal liquor, ammonia liquor, aqua ammonia, aqueous ammonia, or (inaccurately) ammonia, is a solution of ammonia in water. It can be denoted by the symbols NH 3 (aq). Although the name ammonium hydroxide suggests a salt with the composition [NH + 4][OH −
A large shallow container of ammonium hydroxide solution is placed on the floor of the chamber and the chamber is sealed. If the chamber is large or the fuming is to be done for a long time, more than one container may be provided, or the ammonia may be replenished during the process.
In an aqueous solution, it can be expelled by boiling. The aqueous solution of ammonia is basic, and may be described as aqueous ammonia or ammonium hydroxide. [30] The maximum concentration of ammonia in water (a saturated solution) has a specific gravity of 0.880 and is often known as '.880 ammonia'. [31]
80% or more of ammonia is used as fertilizer. Ammonia is also used for the production of plastics, fibres, explosives, nitric acid (via the Ostwald process), and intermediates for dyes and pharmaceuticals. The industry contributes 1% to 2% of global CO 2. [2] Between 18–20 Mt of the gas is transported globally each year. [3]
Ammonium chloride precipitates and is removed by filtration, and the solution is recycled to produce more sodium carbonate. Hou's process eliminates the production of calcium chloride. The byproduct ammonium chloride can be refined, used as a fertilizer and may have greater commercial value than CaCl 2, thus reducing the extent of waste beds.
Slaked lime (calcium hydroxide) or limestone (calcium carbonate) may be worked into soil that is too acidic for plant growth. Fertilizers that improve plant growth are made by neutralizing sulfuric acid (H 2 SO 4) or nitric acid (HNO 3) with ammonia gas (NH 3), making ammonium sulfate or ammonium nitrate. These are salts utilized in the fertilizer.
In the United States, Herbert Henry Dow's use of electrochemistry to produce chemicals from brine was a commercial success that helped to promote the country's chemical industry. [8] The petrochemical industry can be traced back to the oil works of Scottish chemist James Young, and Canadian Abraham Pineo Gesner.
TMAH undergoes simple acid-base reactions to produce tetramethylammonium (TMA) salts whose anion is derived from the acid used. Illustrative is the preparation of tetramethylammonium fluoride: [6] NMe 4 + OH − + HF → NMe 4 + F − + H 2 O. Solutions of TMAH may be used to make other tetramethylammonium salts in metathesis reactions with ...