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Deoxygenation is a chemical reaction involving the removal of oxygen atoms from a molecule. The term also refers to the removal of molecular oxygen (O 2 ) from gases and solvents, a step in air-free technique and gas purifiers .
The Mozingo reduction, also known as Mozingo reaction or thioketal reduction, is a chemical reaction capable of fully reducing a ketone or aldehyde to the corresponding alkane via a dithioacetal. [1] [2] The reaction scheme is as follows: [3]
The Wolff–Kishner reduction is a reaction used in organic chemistry to convert carbonyl functionalities into methylene groups. [1] [2] In the context of complex molecule synthesis, it is most frequently employed to remove a carbonyl group after it has served its synthetic purpose of activating an intermediate in a preceding step.
The second step is the deoxygenation of the pinacolate, which yields the alkene, this second step exploits the oxophilicity of titanium. A proposed mechanism when TiCl 4 and Zn(Cu) are used for the coupling of benzophenone, as proposed in a reference. [3] Note that the mechanism may vary when different conditions are used.
Aldehydes and ketones can be reduced respectively to primary and secondary alcohols. In deoxygenation, the alcohol group can be further reduced and removed altogether by replacement with H. Two broad strategies exist for carbonyl reduction. One method, which is favored in industry, uses hydrogen as the reductant.
The Leuckart reaction is the chemical reaction that converts aldehydes or ketones to amines. The reaction is an example of reductive amination. [1] The reaction, named after Rudolf Leuckart, uses either ammonium formate or formamide as the nitrogen donor and reducing agent. It requires high temperatures, usually between 120 and 130 °C; for the ...
The Barton–McCombie deoxygenation is an organic reaction in which a hydroxy functional group in an organic compound is replaced by a hydrogen to give an alkyl group. [1] [2] It is named after British chemists Sir Derek Harold Richard Barton and Stuart W. McCombie. The Barton-McCombie deoxygenation. This deoxygenation reaction is a radical ...
In organic chemistry, the Myers deoxygenation reaction is an organic redox reaction that reduces an alcohol into an alkyl position by way of an arenesulfonyl hydrazine as a key intermediate. This name reaction is one of four discovered by Andrew Myers that are named after him; this reaction and the Myers allene synthesis reaction involve the ...