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  2. Arrhenius equation - Wikipedia

    en.wikipedia.org/wiki/Arrhenius_equation

    In physical chemistry, the Arrhenius equation is a formula for the temperature dependence of reaction rates.The equation was proposed by Svante Arrhenius in 1889, based on the work of Dutch chemist Jacobus Henricus van 't Hoff who had noted in 1884 that the van 't Hoff equation for the temperature dependence of equilibrium constants suggests such a formula for the rates of both forward and ...

  3. Pre-exponential factor - Wikipedia

    en.wikipedia.org/wiki/Pre-exponential_factor

    Pre-exponential factor. In chemical kinetics, the pre-exponential factor or A factor is the pre-exponential constant in the Arrhenius equation (equation shown below), an empirical relationship between temperature and rate coefficient. It is usually designated by A when determined from experiment, while Z is usually left for collision frequency.

  4. Viscosity models for mixtures - Wikipedia

    en.wikipedia.org/wiki/Viscosity_models_for_mixtures

    Viscosity models for mixtures. The shear viscosity (or viscosity, in short) of a fluid is a material property that describes the friction between internal neighboring fluid surfaces (or sheets) flowing with different fluid velocities. This friction is the effect of (linear) momentum exchange caused by molecules with sufficient energy to move ...

  5. Temperature dependence of viscosity - Wikipedia

    en.wikipedia.org/wiki/Temperature_dependence_of...

    Viscosity depends strongly on temperature. In liquids it usually decreases with increasing temperature, whereas, in most gases, viscosity increases with increasing temperature. This article discusses several models of this dependence, ranging from rigorous first-principles calculations for monatomic gases, to empirical correlations for liquids.

  6. Aquilanti–Mundim deformed Arrhenius model - Wikipedia

    en.wikipedia.org/wiki/Aquilanti–Mundim_Deformed...

    To overcome this problem, Aquilanti and Mundim [3] proposed (2010) a generalized Arrhenius law based on algebraic deformation of the usual exponential function. Starting from the Euler [4] exponential definition given by, (2) defining the deformed exponential function as, (3) Identifying the deformation parameter as a continuous generalization ...

  7. Time–temperature superposition - Wikipedia

    en.wikipedia.org/wiki/Time–temperature...

    The time–temperature superposition principle is a concept in polymer physics and in the physics of glass-forming liquids. [1][2][3] This superposition principle is used to determine temperature-dependent mechanical properties of linear viscoelastic materials from known properties at a reference temperature.

  8. Arrhenius plot - Wikipedia

    en.wikipedia.org/wiki/Arrhenius_plot

    Arrhenius plot. In chemical kinetics, an Arrhenius plot displays the logarithm of a reaction rate constant, ( , ordinate axis) plotted against reciprocal of the temperature ( , abscissa). [1] Arrhenius plots are often used to analyze the effect of temperature on the rates of chemical reactions. For a single rate-limited thermally activated ...

  9. Temperature coefficient - Wikipedia

    en.wikipedia.org/wiki/Temperature_coefficient

    A temperature coefficient describes the relative change of a physical property that is associated with a given change in temperature. For a property R that changes when the temperature changes by dT, the temperature coefficient α is defined by the following equation: Here α has the dimension of an inverse temperature and can be expressed e.g ...

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