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As ammonium nitrate is a salt, both the cation, NH + 4, and the anion, NO − 3, may take part in chemical reactions. Solid ammonium nitrate decomposes on heating. At temperatures below around 300 °C, the decomposition mainly produces nitrous oxide and water: NH 4 NO 3 → N 2 O + 2 H 2 O. At higher temperatures, the following reaction ...
Ceric ammonium nitrate (CAN) is the inorganic compound with the formula (NH 4) 2 [Ce(NO 3) 6]. This orange-red, water-soluble cerium salt is a specialised oxidizing agent in organic synthesis and a standard oxidant in quantitative analysis .
Dissolving ammonium nitrate in water is endothermic. The energy released by the solvation of the ammonium ions and nitrate ions is less than the energy absorbed in breaking up the ammonium nitrate ionic lattice and the attractions between water molecules.
HNO 3 + 2 H 2 SO 4 ⇌ [NO 2] + + [H 3 O] + + 2 HSO − 4; Equilibrium constant: K ≈ 22. The nitronium ion, [NO 2] +, is the active reagent in aromatic nitration reactions. Since nitric acid has both acidic and basic properties, it can undergo an autoprotolysis reaction, similar to the self-ionization of water: 2 HNO 3 ⇌ [NO 2] + + NO − 3 ...
Sodium nitrate is the chemical compound with the formula Na N O 3. This alkali metal nitrate salt is also known as Chile saltpeter (large deposits of which were historically mined in Chile) [4] [5] to distinguish it from ordinary saltpeter, potassium nitrate. The mineral form is also known as nitratine, nitratite or soda niter.
Ammonium nitrite forms naturally in the air and can be prepared by the absorption of equal parts nitrogen dioxide and nitric oxide in aqueous ammonia. [1]It can also be synthesized by oxidizing ammonia with ozone or hydrogen peroxide, or in a precipitation reaction of barium or lead nitrite with ammonium sulfate, or silver nitrite with ammonium chloride, or ammonium perchlorate with potassium ...
Basic cerium(IV) nitrate has the formula Ce(NO 3) 3.OH.3H 2 O. It also forms upon evaporation of solutions of cerium(IV) in nitric acid. [10] When this meets ammonia in water solution it reacts to form ceric ammonium nitrate and ceric hydroxide. [10] Basic dicerium nitrate has the formula Ce 2 O(NO 3) 6 (H 2 O) 6 ·2H 2 O. Again it crystallizes ...
The decomposition of ammonium nitrate is also a common laboratory method for preparing the gas. Equivalently, it can be obtained by heating a mixture of sodium nitrate and ammonium sulfate: [53] 2 NaNO 3 + (NH 4) 2 SO 4 → Na 2 SO 4 + 2 N 2 O + 4 H 2 O. Another method involves the reaction of urea, nitric acid and sulfuric acid: [54]