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The name "seesaw" comes from the observation that it looks like a playground seesaw. Most commonly, four bonds to a central atom result in tetrahedral or, less commonly, square planar geometry. The seesaw geometry occurs when a molecule has a steric number of 5, with the central atom being bonded to 4 other atoms and 1 lone pair (AX 4 E 1 in ...
Geometrical constraints in a molecule can cause a severe distortion of idealized tetrahedral geometry. In compounds featuring "inverted" tetrahedral geometry at a carbon atom, all four groups attached to this carbon are on one side of a plane. [6] The carbon atom lies at or near the apex of a square pyramid with the other four groups at the ...
The name of the seesaw mechanism was given by Tsutomu Yanagida in a Tokyo conference in 1981. There are several types of models, each extending the Standard Model . The simplest version, "Type 1", extends the Standard Model by assuming two or more additional right-handed neutrino fields inert under the electroweak interaction, [ a ] and the ...
Seesaw in 1792 painting by Francisco de Goya A set of conjoined playground seesaws. A seesaw (also known as a teeter-totter) is a long, narrow board supported by a single pivot point, most commonly located at the midpoint between both ends; as one end goes up, the other goes down.
Representative d-orbital splitting diagrams for square planar complexes featuring σ-donor (left) and σ+π-donor (right) ligands. A general d-orbital splitting diagram for square planar (D 4h) transition metal complexes can be derived from the general octahedral (O h) splitting diagram, in which the d z 2 and the d x 2 −y 2 orbitals are degenerate and higher in energy than the degenerate ...
Hydrogen fluoride (HF), like water, is a polar molecule, and due to its polarity it can dissolve many ionic compounds. At atmospheric pressure , its melting point is 189.15 K (−84.00 °C), and its boiling point is 292.69 K (19.54 °C); the difference between the two is a little more than 100 K. HF also makes hydrogen bonds with its neighbor ...
The hydrophobic effect can be quantified by measuring the partition coefficients of non-polar molecules between water and non-polar solvents. The partition coefficients can be transformed to free energy of transfer which includes enthalpic and entropic components, ΔG = ΔH - TΔS. These components are experimentally determined by calorimetry ...
The polarity, dipole moment, polarizability and hydrogen bonding of a solvent determines what type of compounds it is able to dissolve and with what other solvents or liquid compounds it is miscible. Generally, polar solvents dissolve polar compounds best and non-polar solvents dissolve non-polar compounds best; hence "like dissolves like".