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Rodríguez de Tió was born Dolores Rodríguez de Astudillo y Ponce de León [note 1] in San Germán, Puerto Rico.Her father, Sebastián Rodríguez de Astudillo, was one of the founding members of the Ilustre Colegio de Abogados de Puerto Rico (literally, "Illustrious College of Attorneys," the governing body for Spanish attorneys in Puerto Rico, similar to a bar association). [2]