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Immersion zinc plating is an electroless (non-electrolytic) coating process that deposits a thin layer of zinc on a less electronegative metal, by immersion in a solution containing a zinc or zincate ions, Zn(OH) 2− 4. A typical use is plating aluminum with zinc prior to electrolytic or electroless nickel plating.
Such Zinc electroplating or Zinc alloy electroplating maintains a dominant position among other electroplating process options, based upon electroplated tonnage per annum. According to the International Zinc Association, more than 5 million tons are used yearly for both hot dip galvanizing and electroplating. [ 1 ]
The Cronak process is a conventional chromate conversion coating process developed in 1933 by The New Jersey Zinc Company. [1] It involves immersing a zinc or zinc-plated article for 5 to 15 seconds in a chromate solution, typically prepared from sodium dichromate and sulfuric acid . [ 2 ]
Galvanization (also spelled galvanisation) [1] is the process of applying a protective zinc coating to steel or iron, to prevent rusting. The most common method is hot-dip galvanizing, in which the parts are coated by submerging them in a bath of hot, molten zinc. [citation needed]
The process takes advantage of the low solubility of phosphates at medium or high pH. The bath is a solution of phosphoric acid (H 3 PO 4), containing the desired iron, zinc or manganese cations and other additives. [10] The acid reacts with the iron metal producing hydrogen and iron cations: Fe + 2 H 3 O + → Fe 2+ + H 2 + 2 H 2 O
Electroplating, also known as electrochemical deposition or electrodeposition, is a process for producing a metal coating on a solid substrate through the reduction of cations of that metal by means of a direct electric current.
Bethanization is a process patented by the Bethlehem Steel Company to protect steel from corrosion by plating it with zinc, [1] a process similar to electrogalvanization.In advertising materials, Bethlehem Steel claimed the process was more effective than hot dip galvanization, the most common means of using zinc to protect steel.
Solutions prepared from dissolving zinc hydroxide or zinc oxide in a strong alkali like sodium hydroxide, which contains various zincate anions, are used in the metal plating industry, in processes such as immersion zinc plating and electroplating (electrogalvanization). Any of these techniques may be called zincate process. [3]
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