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Selenium tetrafluoride (Se F 4) is an inorganic compound.It is a colourless liquid that reacts readily with water. It can be used as a fluorinating reagent in organic syntheses (fluorination of alcohols, carboxylic acids or carbonyl compounds) and has advantages over sulfur tetrafluoride in that milder conditions can be employed and it is a liquid rather than a gas.
2 KF + SeOCl 2 → 2 KCl + SeOF 2. It can also be produced by the reaction of selenium tetrafluoride with water or selenium dioxide. [2] SeF 4 + H 2 O → SeOF 2 + 2 HF SeF 4 + SeO 2 → 2 SeOF 2. The reaction of selenium dioxide and sulfur tetrafluoride also produces seleninyl fluoride. [4] SeO 2 + SF 4 → SeOF 2 + SOF 2
Selenium tetrafluoride is a laboratory-scale fluorinating agent. The only stable chlorides are selenium tetrachloride (SeCl 4) and selenium monochloride (Se 2 Cl 2), which might be better known as selenium(I) chloride and is structurally analogous to disulfur dichloride.
Pentafluoroselenium hypofluorite can also formed from selenium oxyfluoride and fluorine gas in the presence of potassium fluoride. [4] [5] SeOF 2 + KF → K + [SeOF 3] − — F 2 → K + [SeOF 5] − — F 2 → KF + SeOF 6. The reaction of fluorine gas and Hg(OSeF 5) 2 produces SeOF 6 in much higher yield and with less SeF 6. [3]
Selenium is a component of the amino acids selenocysteine and selenomethionine. In humans, selenium is a trace element nutrient that functions as cofactor for glutathione peroxidases and certain forms of thioredoxin reductase. [1] Selenium-containing proteins are produced from inorganic selenium via the intermediacy of selenophosphate (PSeO 3 3 ...
Diboron tetrafluoride, B 2 F 4, a colorless gas; Dinitrogen tetrafluoride, N 2 F 4 (Tetrafluorohydrazine) ... Selenium tetrafluoride, SeF 4, a liquid at standard ...
Selenium fluoride may refer to: Selenium tetrafluoride (selenium(IV) fluoride), SeF 4; Selenium hexafluoride (selenium(VI) fluoride), SeF 6
The shape of the molecule is a distorted tetrahedron with the O-Se-O angle being 126.2°, the O-Se-F angle being 108.0° and F-Se-F being 94.1°. [3] The Se-F bond length is 1.685 Å and the selenium to oxygen bond is 1.575 Å long.