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Phosphorus pentoxide crystallizes in at least four forms or polymorphs.The most familiar one, a metastable form [1] (shown in the figure), comprises molecules of P 4 O 10.Weak van der Waals forces hold these molecules together in a hexagonal lattice (However, in spite of the high symmetry of the molecules, the crystal packing is not a close packing [2]).
A general formula for such cyclic compounds is [HPO 3] x where x = number of phosphoric units in the molecule. When metaphosphoric acids lose their hydrogens as H +, cyclic anions called metaphosphates are formed. An example of a compound with such an anion is sodium hexametaphosphate (Na 6 P 6 O 18), used as a sequestrant and a food additive.
Diammonium phosphate (DAP; IUPAC name diammonium hydrogen phosphate; chemical formula (NH 4) 2 (HPO 4)) is one of a series of water-soluble ammonium phosphate salts that can be produced when ammonia reacts with phosphoric acid. Solid diammonium phosphate shows a dissociation pressure of ammonia as given by the following expression and equation: [2]
The structure of H 3 PO 5, displaying the intramolecular hydrogen bond. Peroxymonophosphoric acid is a colorless, viscous liquid. It is stabilized by an intramolecular hydrogen bond. [6] The compound is a triprotic acid with acid dissociation constants pK a1 = 1.1, pK a2 = 5.5 and pK a3 = 12.8. In aqueous solutions it slowly undergoes ...
All the hydrogen polyoxides are known or expected to autoionise when in liquid form, with the acidic hydrogen being solvated by other of the neutral polyoxide molecules. H 2 O n ⇌ H + + HO – n 2 H 2 O n ⇌ H 3 O + n + HO – n. The ions can also be formed by protonation or deprotonation of various neutral hydrogen polyoxide by suitably ...
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substitutive naming based on parent hydrides (GeCl 2 Me 2 dichlorodimethylgermane) additive naming ([MnFO 3] fluoridotrioxidomanganese) Additionally there are recommendations for the following: naming of cluster compounds; allowed names for inorganic acids and derivatives; naming of solid phases e.g. non-stoichiometric phases
Cycloalkanes and aromatic compounds can be treated as the main parent chain of the compound, in which case the positions of substituents are numbered around the ring structure. For example, the three isomers of xylene CH 3 C 6 H 4 CH 3 , commonly the ortho- , meta- , and para- forms, are 1,2-dimethylbenzene, 1,3-dimethylbenzene, and 1,4 ...