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In chemistry a donor number (DN) is a quantitative measure of Lewis basicity.A donor number is defined as the negative enthalpy value for the 1:1 adduct formation between a Lewis base and the standard Lewis acid SbCl 5 (antimony pentachloride), in dilute solution in the noncoordinating solvent 1,2-dichloroethane with a zero DN.
In most applications vacancy defects are irrelevant to the intended purpose of a material, as they are either too few or spaced throughout a multi-dimensional space in such a way that force or charge can move around the vacancy [dubious – discuss].
Any non-linear differentiable function, (,), of two variables, and , can be expanded as + +. If we take the variance on both sides and use the formula [11] for the variance of a linear combination of variables (+) = + + (,), then we obtain | | + | | +, where is the standard deviation of the function , is the standard deviation of , is the standard deviation of and = is the ...
For hydrocarbons, the DBE (or IHD) tells us the number of rings and/or extra bonds in a non-saturated structure, which equals the number of hydrogen pairs that are required to make the structure saturated, simply because joining two elements to form a ring or adding one extra bond (e.g., a single bond changed to a double bond) in a structure reduces the need for two H's.
Alternatively, one can graph the expressions and see where they intersect with the line given by the inverse Damköhler number to see the solution for conversion. In the plot below, the y-axis is the inverse Damköhler number and the x-axis the conversion. The rule-of-thumb inverse Damköhler numbers have been placed as dashed horizontal lines.
The aggregation number of micelles can be determined by isothermal titration calorimetry when the aggregation number is not too high. [2] [3] Another classical experiment to determine the mean aggregation number would involve the use of a luminescent probe, a quencher and a known concentration of surfactant. If the concentration of the quencher ...
In crystallography, a Frenkel defect is a type of point defect in crystalline solids, named after its discoverer Yakov Frenkel. [1] The defect forms when an atom or smaller ion (usually cation) leaves its place in the structure, creating a vacancy and becomes an interstitial by lodging in a nearby location. [2]
The cation transport number of the leading solution is then calculated as t + = z + c L A F I Δ t {\displaystyle t_{+}={\frac {z_{+}cLAF}{I\Delta t}}} where z + {\displaystyle z_{+}} is the cation charge, c the concentration, L the distance moved by the boundary in time Δ t , A the cross-sectional area, F the Faraday constant , and I the ...