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  2. Sulfite - Wikipedia

    en.wikipedia.org/wiki/Sulfite

    The structure of the sulfite anion Sulfite is a ligand in coordination chemistry.The structure of Co(ethylenediamine) 2 (SO 3)N 3.[4]The structure of the sulfite anion can be described with three equivalent resonance structures.

  3. Frémy's salt - Wikipedia

    en.wikipedia.org/wiki/Frémy's_salt

    Frémy's salt, being a long-lived free radical, is used as a standard in electron paramagnetic resonance (EPR) spectroscopy, e.g. for quantitation of radicals. Its intense EPR spectrum is dominated by three lines of equal intensity with a spacing of about 13 G (1.3 mT).

  4. Sulfur trioxide - Wikipedia

    en.wikipedia.org/wiki/Sulfur_trioxide

    SO 3 is the anhydride of H 2 SO 4. Thus, it is susceptible to hydration: SO 3 + H 2 O → H 2 SO 4 (Δ f H = −200 kJ/mol) [12] Gaseous sulfur trioxide fumes profusely even in a relatively dry atmosphere owing to formation of a sulfuric acid mist. SO 3 is aggressively hygroscopic. The heat of hydration is sufficient that mixtures of SO 3 and ...

  5. Electrophilic aromatic directing groups - Wikipedia

    en.wikipedia.org/wiki/Electrophilic_aromatic...

    In general, the resonance effect of elements in the third period and beyond is relatively weak. This is mainly because of the relatively poor orbital overlap of the substituent's 3p (or higher) orbital with the 2p orbital of the carbon. Due to a stronger resonance effect and inductive effect than the heavier halogens, fluorine is anomalous.

  6. Trigonal planar molecular geometry - Wikipedia

    en.wikipedia.org/wiki/Trigonal_planar_molecular...

    3), carbonate (CO 2− 3), and guanidinium (C(NH 2) + 3). In organic chemistry, planar, three-connected carbon centers that are trigonal planar are often described as having sp 2 hybridization. [2] [3] Nitrogen inversion is the distortion of pyramidal amines through a transition state that is trigonal planar.

  7. Sulfite sulfate - Wikipedia

    en.wikipedia.org/wiki/Sulfite_sulfate

    Ce 2 (SO 3) 3.3H 2 O + 1 ⁄ 2 O 2 → Ce 2 (SO 3) 2 SO 4 + 3H 2 O Ce 2 (SO 3) 3.3H 2 O + O 2 → Ce 2 SO 3 (SO 4) 2 + 3H 2 O Other rare earth sulfite sulfates can be crystallized as hydrates from a water solution. [3] These sulfite sulfates can be made by at least three methods. One is to dissolve a rare earth oxosulfate in water and then ...

  8. Sulfonate - Wikipedia

    en.wikipedia.org/wiki/Sulfonate

    For example, if the R 2 group is a methyl group and the R 1 group is a trifluoromethyl group, the resulting compound is methyl trifluoromethanesulfonate. Sulfonic esters are used as reagents in organic synthesis, chiefly because the RSO 3 − group is a good leaving group , especially when R is electron-withdrawing.

  9. Sulfur oxide - Wikipedia

    en.wikipedia.org/wiki/Sulfur_oxide

    Sulfur oxide refers to many types of sulfur and oxygen containing compounds such as SO, SO 2, SO 3, S 7 O 2, S 6 O 2, S 2 O 2, etc. Sulfur oxide (SO x) refers to one or more of the following: Lower sulfur oxides (S n O, S 7 O 2 and S 6 O 2) Sulfur monoxide (SO) and its dimer, Disulfur dioxide (S 2 O 2) Sulfur dioxide (SO 2) Sulfur trioxide (SO 3)