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Electrical conduction of metals is a well-known phenomenon and is attributed to the free conduction electrons, which can be measured as sketched in the figure. The current density j is observed to be proportional to the applied electric field and follows Ohm's law where the prefactor is the specific electrical conductivity .
In solid-state physics, the free electron model is a quantum mechanical model for the behaviour of charge carriers in a metallic solid. It was developed in 1927, [1] principally by Arnold Sommerfeld, who combined the classical Drude model with quantum mechanical Fermi–Dirac statistics and hence it is also known as the Drude–Sommerfeld model.
In physics and engineering, a free body diagram (FBD; also called a force diagram) [1] is a graphical illustration used to visualize the applied forces, moments, and resulting reactions on a free body in a given condition. It depicts a body or connected bodies with all the applied forces and moments, and reactions, which act on the body(ies).
In solid-state physics, the valence band and conduction band are the bands closest to the Fermi level, and thus determine the electrical conductivity of the solid. In nonmetals, the valence band is the highest range of electron energies in which electrons are normally present at absolute zero temperature, while the conduction band is the lowest range of vacant electronic states.
Metallic bonding is a type of chemical bonding that arises from the electrostatic attractive force between conduction electrons (in the form of an electron cloud of delocalized electrons) and positively charged metal ions. It may be described as the sharing of free electrons among a structure of positively charged ions .
Here t is the time, p is the average momentum per electron and q, n, m, and τ are respectively the electron charge, number density, mass, and mean free time between ionic collisions. The latter expression is particularly important because it explains in semi-quantitative terms why Ohm's law , one of the most ubiquitous relationships in all of ...
In electrolytes, electrical conduction happens not by band electrons or holes, but by full atomic species traveling, each carrying an electrical charge. The resistivity of ionic solutions (electrolytes) varies tremendously with concentration – while distilled water is almost an insulator, salt water is a reasonable electrical conductor.
Essentially what is occurring is a long chain of momentum transfer between mobile charge carriers; the Drude model of conduction describes this process more rigorously. This momentum transfer model makes metal an ideal choice for a conductor; metals, characteristically, possess a delocalized sea of electrons which gives the electrons enough ...