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  2. Radical (chemistry) - Wikipedia

    en.wikipedia.org/wiki/Radical_(chemistry)

    In chemistry, a radical, also known as a free radical, is an atom, molecule, or ion that has at least one unpaired valence electron. [1] [2] With some exceptions, these unpaired electrons make radicals highly chemically reactive. Many radicals spontaneously dimerize. Most organic radicals have short lifetimes.

  3. Free radical damage to DNA - Wikipedia

    en.wikipedia.org/wiki/Free_radical_damage_to_DNA

    Radiolysis of intracellular water by ionizing radiation creates peroxides, which are relatively stable precursors to hydroxyl radicals. 60%–70% of cellular DNA damage is caused by hydroxyl radicals, [3] yet hydroxyl radicals are so reactive that they can only diffuse one or two molecular diameters before reacting with cellular components.

  4. Hydroxyl radical - Wikipedia

    en.wikipedia.org/wiki/Hydroxyl_radical

    The hydroxyl radical, • HO, is the neutral form of the hydroxide ion (HO –). Hydroxyl radicals are highly reactive and consequently short-lived; however, they form an important part of radical chemistry .

  5. Free-radical addition - Wikipedia

    en.wikipedia.org/wiki/Free-radical_addition

    Chain propagation: A radical reacts with a non-radical to produce a new radical species; Chain termination: Two radicals react with each other to create a non-radical species; In a free-radical addition, there are two chain propagation steps. In one, the adding radical attaches to a multiply-bonded precursor to give a radical with lesser bond ...

  6. Radical disproportionation - Wikipedia

    en.wikipedia.org/wiki/Radical_disproportionation

    Due to the reactive nature of radical molecules, disproportionation proceeds rapidly and requires little to no activation energy. [1] The most thoroughly studied radical disproportionation reactions have been conducted with alkyl radicals, but there are many organic molecules that can exhibit more complex, multi-step disproportionation reactions.

  7. Reactivity–selectivity principle - Wikipedia

    en.wikipedia.org/wiki/Reactivity–selectivity...

    The sulfur radical was found to be more reactive (6*10 8 vs. 1*10 7 M −1.s −1) and less selective (selectivity ratio 76 vs 1200) than the carbon radical. In this case, the effect can be explained by extending the Bell–Evans–Polanyi principle with a factor δ {\displaystyle \delta \,} accounting for transfer of charge from the reactants ...

  8. Reactive oxygen species production in marine microalgae

    en.wikipedia.org/wiki/Reactive_oxygen_species...

    The hydroxyl radical can oxidize membrane lipids and cause nucleic acids and proteins to denature. However, because the radical is so reactive, there is likely not enough time for transport to the cell surface (mean diffusion distance of 4.5 nm). [39]

  9. Reactivity (chemistry) - Wikipedia

    en.wikipedia.org/wiki/Reactivity_(chemistry)

    In fact, the rate of reaction of alkali metals (as evidenced by their reaction with water for example) is a function not only of position within the group but also of particle size. Hydrogen does not react with oxygen—even though the equilibrium constant is very large—unless a flame initiates the radical reaction, which leads to an explosion.

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