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  2. Radical (chemistry) - Wikipedia

    en.wikipedia.org/wiki/Radical_(chemistry)

    In chemistry, a radical, also known as a free radical, is an atom, molecule, or ion that has at least one unpaired valence electron. [1] [2] With some exceptions, these unpaired electrons make radicals highly chemically reactive. Many radicals spontaneously dimerize. Most organic radicals have short lifetimes.

  3. Reactivity–selectivity principle - Wikipedia

    en.wikipedia.org/wiki/Reactivity–selectivity...

    The sulfur radical was found to be more reactive (6*10 8 vs. 1*10 7 M −1.s −1) and less selective (selectivity ratio 76 vs 1200) than the carbon radical. In this case, the effect can be explained by extending the Bell–Evans–Polanyi principle with a factor δ {\displaystyle \delta \,} accounting for transfer of charge from the reactants ...

  4. Hydroxyl radical - Wikipedia

    en.wikipedia.org/wiki/Hydroxyl_radical

    The hydroxyl radical, • HO, is the neutral form of the hydroxide ion (HO –). Hydroxyl radicals are highly reactive and consequently short-lived; however, they form an important part of radical chemistry .

  5. Free radical damage to DNA - Wikipedia

    en.wikipedia.org/wiki/Free_radical_damage_to_DNA

    Radiolysis of intracellular water by ionizing radiation creates peroxides, which are relatively stable precursors to hydroxyl radicals. 60%–70% of cellular DNA damage is caused by hydroxyl radicals, [3] yet hydroxyl radicals are so reactive that they can only diffuse one or two molecular diameters before reacting with cellular components.

  6. Reactivity (chemistry) - Wikipedia

    en.wikipedia.org/wiki/Reactivity_(chemistry)

    In fact, the rate of reaction of alkali metals (as evidenced by their reaction with water for example) is a function not only of position within the group but also of particle size. Hydrogen does not react with oxygen—even though the equilibrium constant is very large—unless a flame initiates the radical reaction, which leads to an explosion.

  7. Radical disproportionation - Wikipedia

    en.wikipedia.org/wiki/Radical_disproportionation

    Due to the reactive nature of radical molecules, disproportionation proceeds rapidly and requires little to no activation energy. [1] The most thoroughly studied radical disproportionation reactions have been conducted with alkyl radicals, but there are many organic molecules that can exhibit more complex, multi-step disproportionation reactions.

  8. Free-radical addition - Wikipedia

    en.wikipedia.org/wiki/Free-radical_addition

    Chain propagation: A radical reacts with a non-radical to produce a new radical species; Chain termination: Two radicals react with each other to create a non-radical species; In a free-radical addition, there are two chain propagation steps. In one, the adding radical attaches to a multiply-bonded precursor to give a radical with lesser bond ...

  9. Persistent radical effect - Wikipedia

    en.wikipedia.org/wiki/Persistent_radical_effect

    The persistent radical effect (PRE) in chemistry describes and explains the selective product formation found in certain free-radical cross-reactions. In these type of reactions, different radicals compete in secondary reactions. The so-called persistent (long-lived) radicals do not self-terminate and only react in cross-couplings.

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