Search results
Results from the WOW.Com Content Network
Diatomic molecules (from Greek di- 'two') are molecules composed of only two atoms, of the same or different chemical elements. If a diatomic molecule consists of two atoms of the same element, such as hydrogen ( H 2 ) or oxygen ( O 2 ), then it is said to be homonuclear .
Diatomic molecules consist of a bond between only two atoms. They can be broken into two categories: homonuclear and heteronuclear. A homonuclear diatomic molecule is one composed of two atoms of the same element. Examples are H 2, O 2, and N 2. A heteronuclear diatomic molecule is composed of two atoms of two different elements.
Heteronuclear molecules. A heteronuclear molecule is a molecule composed of atoms of more than one chemical element. [1] [2] For example, a molecule of water (H 2 O) is heteronuclear because it has atoms of two different elements, hydrogen (H) and oxygen (O). Similarly, a heteronuclear ion is an ion that contains atoms of more than one chemical ...
Homonuclear diatomic molecules include hydrogen (H 2), oxygen (O 2), nitrogen (N 2) and all of the halogens. Ozone (O 3) is a common triatomic homonuclear molecule. Homonuclear tetratomic molecules include arsenic (As 4) and phosphorus (P 4). Allotropes are different chemical forms of the same element (not containing any other element). In that ...
Homonuclear diatomic molecules also show this kind of spectra. The selection rules, however, are a bit different. Conclusion: Both homo- and hetero-nuclear diatomic molecules show rovibrational spectra. A Q-branch is absent in the spectra of heteronuclear diatomic molecules.
For heteronuclear diatomic molecules, the u/g symbol does not correspond to any exact symmetry of the electronic molecular Hamiltonian. In the case of less symmetric molecules the molecular term symbol contains the symbol of the group representation to which the molecular electronic state belongs. It has the general form:
Heteronuclear molecules and molecules that have more than two species are also called exciplex molecules (originally short for excited complex). Excimers are often diatomic and are composed of two atoms or molecules that would not bond if both were in the ground state. The lifetime of an excimer is very short, on the order of nanoseconds.
Molecular orbitals are said to be degenerate if they have the same energy. For example, in the homonuclear diatomic molecules of the first ten elements, the molecular orbitals derived from the p x and the p y atomic orbitals result in two degenerate bonding orbitals (of low energy) and two degenerate antibonding orbitals (of high energy). [13]