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In an aqueous solution, precipitation is the "sedimentation of a solid material (a precipitate) from a liquid solution". [1] [2] The solid formed is called the precipitate. [3] In case of an inorganic chemical reaction leading to precipitation, the chemical reagent causing the solid to form is called the precipitant. [4]
For example, a solution of table salt, also known as sodium chloride (NaCl), in water would be represented as Na + (aq) + Cl − (aq). The word aqueous (which comes from aqua) means pertaining to, related to, similar to, or dissolved in, water. [1] [2] As water is an excellent solvent and is also naturally abundant, it is a ubiquitous solvent ...
The following chart shows the solubility of various ionic compounds in water at 1 atm pressure and room temperature (approx. 25 °C, 298.15 K). "Soluble" means the ionic compound doesn't precipitate, while "slightly soluble" and "insoluble" mean that a solid will precipitate; "slightly soluble" compounds like calcium sulfate may require heat to precipitate.
In chemistry, coprecipitation (CPT) or co-precipitation is the carrying down by a precipitate of substances normally soluble under the conditions employed. [1] Analogously, in medicine, coprecipitation (referred to as immunoprecipitation) is specifically "an assay designed to purify a single antigen from a complex mixture using a specific antibody attached to a beaded support".
For example, the precipitation of silver chloride from a mixture of silver nitrate and cobalt hexammine chloride delivers the nitrate salt of the cobalt complex: 3 AgNO 3 + [Co(NH 3) 6]Cl 3 → 3 AgCl + [Co(NH 3) 6](NO 3) 3. The reactants need not be highly soluble for metathesis reactions to take place.
multilang-version for File:Chemical precipitation diagram.svg: File usage. The following 5 pages use this file: Chemical reaction; Precipitation (chemistry) Solubility;
The term precipitation is normally reserved for describing a phase change from a colloid dispersion to a solid (precipitate) when it is subjected to a perturbation. [19] Aggregation causes sedimentation or creaming, therefore the colloid is unstable: if either of these processes occur the colloid will no longer be a suspension.
Gravimetric analysis describes a set of methods used in analytical chemistry for the quantitative determination of an analyte (the ion being analyzed) based on its mass. The principle of this type of analysis is that once an ion's mass has been determined as a unique compound, that known measurement can then be used to determine the same analyte's mass in a mixture, as long as the relative ...