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A number of materials contract on heating within certain temperature ranges; this is usually called negative thermal expansion, rather than "thermal contraction".For example, the coefficient of thermal expansion of water drops to zero as it is cooled to 3.983 °C (39.169 °F) and then becomes negative below this temperature; this means that water has a maximum density at this temperature, and ...
To distinguish these two thermal expansion equations of state, the latter one is called pressure-dependent thermal expansion equation of state. To deveop the pressure-dependent thermal expansion equation of state, in an compression process at room temperature from (V 0, T 0, P 0) to (V 1, T 0,P 1), a general form of volume is expressed as
We assume the expansion occurs without exchange of heat (adiabatic expansion). Doing this work , air inside the cylinder will cool to below the target temperature. To return to the target temperature (still with a free piston), the air must be heated, but is no longer under constant volume, since the piston is free to move as the gas is reheated.
In thermodynamics, the Volume Correction Factor (VCF), also known as Correction for the effect of Temperature on Liquid (CTL), is a standardized computed factor used to correct for the thermal expansion of fluids, primarily, liquid hydrocarbons at various temperatures and densities. [1]
Quick heating or cooling causes thermal expansion or contraction respectively, this localized movement of material causes thermal stresses. Imagine heating a cylinder, first the surface rises in temperature and the center remains the same initial temperature. After some time the center of the cylinder will reach the same temperature as the surface.
β is the coefficient of volume expansion (equal to approximately 1/T for ideal gases) T s is the surface temperature; T ∞ is the bulk temperature; L is the vertical length; D is the diameter; ν is the kinematic viscosity. The L and D subscripts indicate the length scale basis for the Grashof number.
The volume ratio / is called the "isentropic expansion ratio". (For the Otto cycle is the same as the compression ratio /). Mechanically this is the expansion of the hot gaseous mixture in the cylinder known as expansion (power) stroke.
Absolute cylinder pressure is used to calculate the dynamic compression ratio, using the following formula: = where is a polytropic value for the ratio of specific heats for the combustion gases at the temperatures present (this compensates for the temperature rise caused by compression, as well as heat lost to the cylinder)