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Electrons in solids have a chemical potential, defined the same way as the chemical potential of a chemical species: The change in free energy when electrons are added or removed from the system. In the case of electrons, the chemical potential is usually expressed in energy per particle rather than energy per mole, and the energy per particle ...
Le Chatelier–Braun principle analyzes the qualitative behaviour of a thermodynamic system when a particular one of its externally controlled state variables, say , changes by an amount , the 'driving change', causing a change , the 'response of prime interest', in its conjugate state variable , all other externally controlled state variables remaining constant.
The flames caused as a result of a fuel undergoing combustion (burning) Air pollution abatement equipment provides combustion control for industrial processes.. Combustion, or burning, [1] is a high-temperature exothermic redox chemical reaction between a fuel (the reductant) and an oxidant, usually atmospheric oxygen, that produces oxidized, often gaseous products, in a mixture termed as smoke.
Chemical thermodynamics is the study of the interrelation of heat and work with chemical reactions or with physical changes of state within the confines of the laws of thermodynamics. Chemical thermodynamics involves not only laboratory measurements of various thermodynamic properties, but also the application of mathematical methods to the ...
Chemical energy is the energy of chemical substances that is released when the substances undergo a chemical reaction and transform into other substances. Some examples of storage media of chemical energy include batteries, [1] food, and gasoline (as well as oxygen gas, which is of high chemical energy due to its relatively weak double bond [2] and indispensable for chemical-energy release in ...
Chemical reactions are determined by the laws of thermodynamics. Reactions can proceed by themselves if they are exergonic, that is if they release free energy. The associated free energy change of the reaction is composed of the changes of two different thermodynamic quantities, enthalpy and entropy: [17]
A certain amount of energy, which may be large enough, is required to remove an electron from an atom or a molecule in its ground state. [12] [13] In chemi-ionization processes, the energy consumed by the ionization must be stored in atoms or molecules in a form of potencial energy or can be obtained from an accompanying exothermic chemical change (for example, from a formation of a new ...
The fugacity of a condensed phase (liquid or solid) is defined the same way as for a gas: = and = It is difficult to measure fugacity in a condensed phase directly; but if the condensed phase is saturated (in equilibrium with the vapor phase), the chemical potentials of the two phases are equal (μ c = μ g).