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Formally, a carbanion is the conjugate base of a carbon acid: R 3 CH + B − → R 3 C − + HB. where B stands for the base. The carbanions formed from deprotonation of alkanes (at an sp 3 carbon), alkenes (at an sp 2 carbon), arenes (at an sp 2 carbon), and alkynes (at an sp carbon) are known as alkyl, alkenyl , aryl, and alkynyl anions ...
2D diagram of mellitate C 12 O 6− 12, one of the oxocarbon anions. Black circles are carbon atoms, red circles are oxygen atoms. Each blue halo represents one half of a negative charge. In chemistry, an oxocarbon anion is a negative ion consisting solely of carbon and oxygen atoms, and therefore having the general formula C x O n−
Carbon trioxide (CO 3) is an unstable oxide of carbon (an oxocarbon). The possible isomers of carbon trioxide include ones with molecular symmetry point groups C s , D 3h , and C 2v . The C 2v state, consisting of a dioxirane , has been shown to be the ground state of the molecule. [ 1 ]
In organic chemistry, a carbonyl group is a functional group with the formula C=O, composed of a carbon atom double-bonded to an oxygen atom, and it is divalent at the C atom. It is common to several classes of organic compounds (such as aldehydes, ketones and carboxylic acid), as part of many larger functional groups. A compound containing a ...
The carbon atom lies at or near the apex of a square pyramid with the other four groups at the corners. [ 7 ] [ 8 ] The simplest examples of organic molecules displaying inverted tetrahedral geometry are the smallest propellanes , such as [1.1.1]propellane ; or more generally the paddlanes , [ 9 ] and pyramidane ([3.3.3.3]fenestrane).
A carbon–oxygen bond is a polar covalent bond between atoms of carbon and oxygen. [1] [2] [3]: 16–22 Carbon–oxygen bonds are found in many inorganic compounds such as carbon oxides and oxohalides, carbonates and metal carbonyls, [4] and in organic compounds such as alcohols, ethers, and carbonyl compounds.
For typical ionic solids, the cations are smaller than the anions, and each cation is surrounded by coordinated anions which form a polyhedron.The sum of the ionic radii determines the cation-anion distance, while the cation-anion radius ratio + / (or /) determines the coordination number (C.N.) of the cation, as well as the shape of the coordinated polyhedron of anions.
This trend can be inferred by the hydride ion affinity values (231, 246, 273, and 312 kcal/mol for (CH 3) 3 C +, (CH 3) 2 CH +, CH 3 CH + 2, and CH + 3). [9] The effect of alkyl substitution is a strong one: tertiary cations are stable and many are directly observable in superacid media. The stabilization by alkyl groups is explained by ...