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The polymer separated from the glass as a clear plastic sheet, which Röhm gave the trademarked name Plexiglas in 1933. [5] Both Perspex and Plexiglas were commercialized in the late 1930s. In the United States, E.I. du Pont de Nemours & Company (now DuPont Company) subsequently introduced its own product under the trademark Lucite.
Cast acrylic has a better ability to be reworked hot and it is known for its superior surface finish and optical properties. Also cast acrylic is more scratch resistant than extruded acrylic. Cast acrylic is also preferred over extruded in applications that require machinings, such as turning on Engine Lathe or milling/drilling.
Polymethyl methacrylate is the clear break-resistant sheeting sold as acrylic glass (or simply acrylic sheet) or under the trade name Plexiglas, Perspex, etc. Polyacrylates are used in cosmetic products as rheology modifiers and film formers, and these are typically polymers of acrylic acid fluids.
ASA can be made by either a reaction process of all three monomers (styrene, acrylonitrile, acrylic ester) or a graft process, although the graft process is the typical method. A grafted acrylic ester elastomer is introduced during the copolymerization of styrene and acrylonitrile. The elastomer is introduced as a powder. [11]
Acrylonitrile butadiene styrene (ABS) (chemical formula (C 8 H 8) x · (C 4 H 6) y · (C 3 H 3 N) z) is a common thermoplastic polymer. Its glass transition temperature is approximately 105 °C (221 °F). [4] ABS is amorphous and therefore has no true melting point.
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