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The lanthanide contraction is the greater-than-expected decrease in atomic radii and ionic radii of the elements in the lanthanide series, from left to right. It is caused by the poor shielding effect of nuclear charge by the 4f electrons along with the expected periodic trend of increasing electronegativity and nuclear charge on moving from left to right.
The trivalent lanthanide ions decrease steadily in size from lanthanum to lutetium, an effect known as the lanthanide contraction. [31] From lanthanum to dysprosium , the coordination number is maintained at 9 with a tricapped trigonal prismatic structure, although starting from samarium the capping water molecules are no longer equally ...
The lanthanide contraction, i.e. the reduction in size of the Ln 3+ ion from La 3+ (103 pm) to Lu 3+ (86.1 pm), is often explained by the poor shielding of the 5s and 5p electrons by the 4f electrons. [18] Lanthanide oxides: clockwise from top center: praseodymium, cerium, lanthanum, neodymium, samarium and gadolinium.
Lanthanide dodecaborides, LnB 12, are formed by the heavier smaller lanthanides from Gd to Lu. With the exception YbB 12 (where Yb takes an intermediate valence and is a Kondo insulator), the dodecaborides are all metallic compounds. They all have the UB 12 structure containing a 3 dimensional framework of cubooctahedral B 12 clusters. [36]
The lanthanide contraction only partially accounts for this anomaly. [11] Because the 6s 2 orbital is contracted by relativistic effects and may therefore only weakly contribute to any chemical bonding, Hg–Hg bonding must be mostly the result of van der Waals forces. [11] [13] [14] Mercury gas is mostly monatomic, Hg(g).
Hafnium diboride belongs to the class of ultra-high temperature ceramics, a type of refractory ceramic composed of hafnium and boron. It has a melting temperature of about 3250 °C. It is an unusual ceramic, having relatively high thermal and electrical conductivities, properties it shares with isostructural titanium diboride and zirconium ...
The reductions in atomic size due to the interjection of the d- and f-blocks are referred to as, respectively, the 'scandide' or 'd-block contraction', [n 3] and the 'lanthanide contraction'. [13] Relativistic effects also "increase the binding energy", and hence ionisation energy, of the electrons in "the 6s shell in gold and mercury, and the ...
Group 12, by modern IUPAC numbering, [1] is a group of chemical elements in the periodic table. It includes zinc (Zn), cadmium (Cd), mercury (Hg), [ 2 ] [ 3 ] [ 4 ] and copernicium (Cn). [ 5 ] Formerly this group was named IIB (pronounced as "group two B", as the "II" is a Roman numeral ) by CAS and old IUPAC system.