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Biphenyl (also known as diphenyl, phenylbenzene, 1,1′-biphenyl, lemonene [4] or BP) is an organic compound that forms colorless crystals. Particularly in older literature, compounds containing the functional group consisting of biphenyl less one hydrogen (the site at which it is attached) may use the prefixes xenyl or diphenylyl .
The bisphenols (/ ˈ b ɪ s f ɪ n ɒ l /) are a group of industrial chemical compounds related to diphenylmethane; commonly used in the creation of plastics and epoxy resins. [ 1 ] [ 2 ] [ 3 ] Most are based on two hydroxyphenyl functional groups linked by a methylene bridge .
The industrial synthesis of 4,4′-biphenol was developed by Allan Hay in the 1960s. [ 2 ] [ 3 ] As the direct oxidative coupling of phenol gives a mixture of isomers, [ 4 ] [ 5 ] 4,4′-biphenol is instead prepared from 2,6-di-tert-butylphenol , where para-coupling is the only possibility. [ 3 ]
The synthesis of BPA still follows Dianin's general method, with the fundamentals changing little in 130 years. The condensation of acetone (hence the suffix 'A' in the name) [ 33 ] with two equivalents of phenol is catalyzed by a strong acid, such as concentrated hydrochloric acid , sulfuric acid , or a solid acid resin such as the sulfonic ...
3 Synthesis and applications. 4 Safety ... refers to a class of organic compounds consisting of a biphenyl structure with two hydroxyl groups attached. The most ...
In enzymology, a biphenyl synthase (EC 2.3.1.177) is an enzyme that catalyzes the chemical reaction: . 3 malonyl-CoA + benzoyl-CoA 4 CoA + 3,5-dihydroxybiphenyl + 4 CO 2. Thus, the two substrates of this enzyme are malonyl-CoA and benzoyl-CoA, whereas its three products are CoA, 3,5-dihydroxybiphenyl, and CO 2.
Bromobenzene is used to introduce a phenyl group into other compounds. One method involves its conversion to the Grignard reagent , phenylmagnesium bromide . This reagent can be used, e.g. in the reaction with carbon dioxide to prepare benzoic acid . [ 4 ]
BINAP (2,2′-bis(diphenylphosphino)-1,1′-binaphthyl) is an organophosphorus compound. This chiral diphosphine ligand is widely used in asymmetric synthesis . It consists of a pair of 2-diphenylphosphino naphthyl groups linked at the 1 and 1′ positions.