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[4] [7] A recent comparison showed that state-of-the-art nickel based water electrolysers with alkaline electrolytes lead to competitive or even better efficiencies than acidic polymer electrolyte membrane water electrolysis with platinum group metal based electrocatalysts. [8] The technology has a long history in the chemical industry.
Proton exchange membrane (PEM) electrolysis is the electrolysis of water in a cell equipped with a solid polymer electrolyte (SPE) [3] that is responsible for the conduction of protons, separation of product gases, and electrical insulation of the electrodes. The PEM electrolyzer was introduced to overcome the issues of partial load, low ...
In the chloralkali process (electrolysis of brine) a water/sodium chloride mixture is only half the electrolysis of water since the chloride ions are oxidized to chlorine rather than water being oxidized to oxygen. Thermodynamically, this would not be expected since the oxidation potential of the chloride ion is less than that of water, but the ...
The general function of the electrolyzer cell is to split water in the form of steam into pure H 2 and O 2. Steam is fed into the porous cathode. When a voltage is applied, the steam moves to the cathode-electrolyte interface and is reduced to form pure H 2 and oxygen ions. The hydrogen gas then diffuses back up through the cathode and is ...
In alkaline anion-exchange membrane fuel cell, aqueous KOH is replaced with a solid polymer electrolyte membrane, that can conduct hydroxide ions. This could overcome the problems of electrolyte leakage and carbonate precipitation, though still taking advantage of benefits of operating a fuel cell in an alkaline environment.
Polymer electrolyte membrane electrolysis is a technique by which proton-exchange membranes are used to decompose water into hydrogen and oxygen gas. [21] The proton-exchange membrane allows for the separation of produced hydrogen from oxygen, allowing either product to be exploited as needed.
A membrane electrode assembly (MEA) is an assembled stack of proton-exchange membranes (PEM) or alkali anion exchange membrane (AAEM), catalyst and flat plate electrode used in fuel cells and electrolyzers.
Both of these mechanisms can be seen in industrial practices at the cathode side of the electrolyzer where hydrogen evolution occurs. In acidic conditions, it is referred to as proton exchange membrane electrolysis or PEM, while in alkaline conditions it is referred to simply as alkaline electrolysis. Historically, alkaline electrolysis has ...