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  2. Paschen's law - Wikipedia

    en.wikipedia.org/wiki/Paschen's_law

    If the electron is in an electric field of 43 MV/m, it will be accelerated and acquire 21.5 eV of energy in 0.5 μm of travel in the direction of the field. The first ionization energy needed to dislodge an electron from nitrogen molecule is about 15.6 eV. The accelerated electron will acquire more than enough energy to ionize a nitrogen molecule.

  3. Morse potential - Wikipedia

    en.wikipedia.org/wiki/Morse_potential

    The Morse potential, named after physicist Philip M. Morse, is a convenient interatomic interaction model for the potential energy of a diatomic molecule.It is a better approximation for the vibrational structure of the molecule than the quantum harmonic oscillator because it explicitly includes the effects of bond breaking, such as the existence of unbound states.

  4. Potential energy surface - Wikipedia

    en.wikipedia.org/wiki/Potential_energy_surface

    Energy profiles describe potential energy as a function of geometrical variables (PES in any dimension are independent of time and temperature). H+H2 Potential energy surface. We have different relevant elements in the 2-D PES: The 2-D plot shows the minima points where we find reactants, the products and the saddle point or transition state.

  5. Chemical potential - Wikipedia

    en.wikipedia.org/wiki/Chemical_potential

    Movement of molecules from higher chemical potential to lower chemical potential is accompanied by a release of free energy. Therefore, it is a spontaneous process . Another example, not based on concentration but on phase, is an ice cube on a plate above 0 °C.

  6. Lennard-Jones potential - Wikipedia

    en.wikipedia.org/wiki/Lennard-Jones_potential

    In computational chemistry, molecular physics, and physical chemistry, the Lennard-Jones potential (also termed the LJ potential or 12-6 potential; named for John Lennard-Jones) is an intermolecular pair potential. Out of all the intermolecular potentials, the Lennard-Jones potential is probably the one that has been the most extensively studied.

  7. Thermodynamic potential - Wikipedia

    en.wikipedia.org/wiki/Thermodynamic_potential

    A thermodynamic potential (or more accurately, a thermodynamic potential energy) [1] [2] is a scalar quantity used to represent the thermodynamic state of a system. Just as in mechanics , where potential energy is defined as capacity to do work, similarly different potentials have different meanings.

  8. Molecular vibration - Wikipedia

    en.wikipedia.org/wiki/Molecular_vibration

    A molecular vibration is a periodic motion of the atoms of a molecule relative to each other, such that the center of mass of the molecule remains unchanged. The typical vibrational frequencies range from less than 10 13 Hz to approximately 10 14 Hz, corresponding to wavenumbers of approximately 300 to 3000 cm −1 and wavelengths of approximately 30 to 3 μm.

  9. Water potential - Wikipedia

    en.wikipedia.org/wiki/Water_potential

    Water potential is the potential energy of water per unit volume relative to pure water in reference conditions. Water potential quantifies the tendency of water to move from one area to another due to osmosis , gravity , mechanical pressure and matrix effects such as capillary action (which is caused by surface tension ).