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Absolute zero is the lowest limit of the thermodynamic temperature scale; a state at which the enthalpy and entropy of a cooled ideal gas reach their minimum value. The fundamental particles of nature have minimum vibrational motion, retaining only quantum mechanical, zero-point energy -induced particle motion.
At absolute zero (zero kelvins) the system must be in a state with the minimum possible energy. Entropy is related to the number of accessible microstates, and there is typically one unique state (called the ground state) with minimum energy. [1] In such a case, the entropy at absolute zero will be exactly zero.
In 1954, with absolute zero having been experimentally determined to be about −273.15 °C per the definition of °C then in use, Resolution 3 of the 10th General Conference on Weights and Measures (CGPM) introduced a new internationally standardized Kelvin scale which defined the triple point as exactly 273.15 + 0.01 = 273.16 degrees Kelvin.
At absolute zero temperature, the system is in the state with the minimum thermal energy, the ground state. The constant value (not necessarily zero) of entropy at this point is called the residual entropy of the system. With the exception of non-crystalline solids (e.g. glass) the residual entropy of a system is typically close to zero. [2]
Its numerical zero point, 0 K, is at the absolute zero of temperature. Since May 2019, the kelvin has been defined through particle kinetic theory , and statistical mechanics. In the International System of Units (SI), the magnitude of the kelvin is defined in terms of the Boltzmann constant , the value of which is defined as fixed by ...
Rankine (°R or °Ra), which uses the Fahrenheit scale, adjusted so that 0 degrees Rankine is equal to absolute zero. Unlike the degree Fahrenheit and degree Celsius, the kelvin is no longer referred to or written as a degree (but was before 1967 [1] [2] [3]). The kelvin is the primary unit of temperature measurement in the physical sciences ...
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Similar to the Kelvin scale, which was first proposed in 1848, [1] zero on the Rankine scale is absolute zero, but a temperature difference of one Rankine degree (°R or °Ra) is defined as equal to one Fahrenheit degree, rather than the Celsius degree used on the Kelvin scale.