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Pearlite is a two-phased, lamellar (or layered) structure composed of alternating layers of ferrite (87.5 wt%) and cementite (12.5 wt%) that occurs in some steels and cast irons. During slow cooling of an iron-carbon alloy, pearlite forms by a eutectoid reaction as austenite cools below 723 °C (1,333 °F) (the eutectoid temperature).
[2] [3] Acicular ferrite is a fine Widmanstätten constituent, which is nucleated by an optimum intragranular dispersion of oxide/sulfide/silicate particles. The interlocking nature of acicular ferrite, together with its fine grain size (0.5 to 5 μm with aspect ratio from 3:1 to 10:1), provides maximum resistance to crack propagation by cleavage.
Bainite is a plate-like microstructure that forms in steels at temperatures of 125–550 °C (depending on alloy content). [1] First described by E. S. Davenport and Edgar Bain, [2] [3] it is one of the products that may form when austenite (the face-centered cubic crystal structure of iron) is cooled past a temperature where it is no longer thermodynamically stable with respect to ferrite ...
Below 912 °C (1,674 °F), iron has a body-centered cubic (bcc) crystal structure and is known as α-iron or ferrite.It is thermodynamically stable and a fairly soft metal. α-Fe can be subjected to pressures up to ca. 15 GPa before transforming into a high-pressure form termed ε-Fe discussed below.
In the iron–carbon system (i.e. plain-carbon steels and cast irons) it is a common constituent because ferrite can contain at most 0.02wt% of uncombined carbon. [6] Therefore, in carbon steels and cast irons that are slowly cooled, a portion of the carbon is in the form of cementite. [ 7 ]
This increases the brittleness of the steel in a way that can only be relieved by recrystallizing. Widmanstätten structures made from ferrite sometimes occur in carbon steel, if the carbon content is below but near the eutectoid composition (~ 0.8% carbon). This occurs as long needles of ferrite within the pearlite. [16]
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