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Pearlite is a two-phased, lamellar (or layered) structure composed of alternating layers of ferrite (87.5 wt%) and cementite (12.5 wt%) that occurs in some steels and cast irons. During slow cooling of an iron-carbon alloy, pearlite forms by a eutectoid reaction as austenite cools below 723 °C (1,333 °F) (the eutectoid temperature). Pearlite ...
Austenite, also known as gamma-phase iron (γ-Fe), is a metallic, non-magnetic allotrope of iron or a solid solution of iron with an alloying element. [1] In plain-carbon steel , austenite exists above the critical eutectoid temperature of 1000 K (727 °C); other alloys of steel have different eutectoid temperatures.
For a eutectoid steel (0.76% C), between 6 and 10% of austenite, called retained austenite, will remain. The percentage of retained austenite increases from insignificant for less than 0.6% C steel, to 13% retained austenite at 0.95% C and 30–47% retained austenite for a 1.4% carbon steel. A very rapid quench is essential to create martensite.
The mixture adopts a lamellar structure called pearlite. Since bainite and pearlite each contain α-Fe as a component, any iron-carbon alloy will contain some amount of α-Fe if it is allowed to reach equilibrium at room temperature. The amount of α-Fe depends on the cooling process.
In carbon steel, cementite precipitates from austenite as austenite transforms to ferrite on slow cooling, or from martensite during tempering. An intimate mixture with ferrite, the other product of austenite, forms a lamellar structure called pearlite. The iron-carbon phase diagram
Austenite is slightly undercooled when quenched below Eutectoid temperature. When given more time, stable microconstituents can form: ferrite and cementite. Coarse pearlite is produced when atoms diffuse rapidly after phases that form pearlite nucleate. This transformation is complete at the pearlite finish time (P f).
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Austenite has much higher stacking-fault energy than martensite or pearlite, lowering the wear resistance and increasing the chances of galling, although some or most of the retained austenite can be transformed into martensite by cold and cryogenic treatments prior to tempering.