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  2. Water-reactive substances - Wikipedia

    en.wikipedia.org/wiki/Water-reactive_substances

    Water-reactive substances [1] are those that spontaneously undergo a chemical reaction with water, often noted as generating flammable gas. [2] Some are highly reducing in nature. [ 3 ] Notable examples include alkali metals , lithium through caesium , and alkaline earth metals , magnesium through barium .

  3. Chemical reaction - Wikipedia

    en.wikipedia.org/wiki/Chemical_reaction

    Also, some relatively minor additions to the reaction can be indicated above the reaction arrow; examples of such additions are water, heat, illumination, a catalyst, etc. Similarly, some minor products can be placed below the arrow, often with a minus sign. An example of organic reaction: oxidation of ketones to esters with a peroxycarboxylic acid

  4. Reaction mechanism - Wikipedia

    en.wikipedia.org/wiki/Reaction_mechanism

    A reaction step involving two molecular entities is called bimolecular. A reaction step involving three molecular entities is called trimolecular or termolecular. In general, reaction steps involving more than three molecular entities do not occur, because is statistically improbable in terms of Maxwell distribution to find such a transition state.

  5. Cohesion (chemistry) - Wikipedia

    en.wikipedia.org/wiki/Cohesion_(chemistry)

    Mercury exhibits more cohesion than adhesion with glass Rain water flux from a canopy. Among the forces that govern drop formation: cohesion, surface tension, Van der Waals force, Plateau–Rayleigh instability. Water, for example, is strongly cohesive as each molecule may make four hydrogen bonds to other water molecules in a tetrahedral ...

  6. Marcus theory - Wikipedia

    en.wikipedia.org/wiki/Marcus_theory

    In outer sphere redox reactions no bonds are formed or broken; only an electron transfer (ET) takes place. A quite simple example is the Fe 2+ /Fe 3+ redox reaction, the self exchange reaction which is known to be always occurring in an aqueous solution containing the aquo complexes [Fe(H 2 O) 6] 2+ and [Fe(H 2 O)6] 3+.

  7. Molecularity - Wikipedia

    en.wikipedia.org/wiki/Molecularity

    Catalytic reactions are often three-component, but in practice a complex of the starting materials is first formed and the rate-determining step is the reaction of this complex into products, not an adventitious collision between the two species and the catalyst. For example, in hydrogenation with a metal catalyst, molecular dihydrogen first ...

  8. Talk:Molecularity - Wikipedia

    en.wikipedia.org/wiki/Talk:Molecularity

    A reaction involving one molecular entity is called unimolecular. A reaction involving two molecular entities is called bimolecular. A reaction involving three molecular entities is called termolecular. Termolecular reactions in homogenous solutions or gas mixtures are very rare . However the term Termolecular is also used to refer to three ...

  9. Self-ionization of water - Wikipedia

    en.wikipedia.org/wiki/Self-ionization_of_water

    The self-ionization of water (also autoionization of water, autoprotolysis of water, autodissociation of water, or simply dissociation of water) is an ionization reaction in pure water or in an aqueous solution, in which a water molecule, H 2 O, deprotonates (loses the nucleus of one of its hydrogen atoms) to become a hydroxide ion, OH −.