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The term molecule may or may not be used to refer to a polyatomic ion, depending on the definition used. The prefix poly-carries the meaning "many" in Greek, but even ions of two atoms are commonly described as polyatomic. [2] In older literature, a polyatomic ion may instead be referred to as a radical (or less commonly, as a radical group).
The cation is always named first. Ions can be metals, non-metals or polyatomic ions. Therefore, the name of the metal or positive polyatomic ion is followed by the name of the non-metal or negative polyatomic ion. The positive ion retains its element name whereas for a single non-metal anion the ending is changed to -ide.
In chemistry, the pentazenium cation (also known as pentanitrogen) is a positively-charged polyatomic ion with the chemical formula N + 5 and structure N−N−N−N−N.Together with solid nitrogen polymers and the azide anion, it is one of only three poly-nitrogen species obtained in bulk quantities.
For molecules and polyatomic ions the coordination number of an atom is determined by simply counting the other atoms to which it is bonded (by either single or multiple bonds). [1] For example, [Cr(NH 3 ) 2 Cl 2 Br 2 ] − has Cr 3+ as its central cation, which has a coordination number of 6 and is described as hexacoordinate .
The best known polycation of mercury is Hg 2+ 2, in which mercury has a formal oxidation state of +1. The Hg 2+ 2 ion was perhaps the first metal-metal bonded species confirmed. The presence of the Hg 2+ 2 ion in solution was shown by Ogg in 1898. [7] In 1900, Baker showed the presence of HgCl dimers in the vapour phase. [8] The presence of Hg 2+
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Cations are positively (+) charged ions while anions are negatively (−) charged. This can be remembered with the help of the following mnemonics. Cats have paws ⇔ Cations are pawsitive. [23] Ca+ion: The letter t in cation looks like a + (plus) sign. [24] An anion is a negative ion. (An egative ion ⇒ Anion). [25]