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Gallium nitride (Ga N) is a binary III/V direct bandgap semiconductor commonly used in blue light-emitting diodes since the 1990s. The compound is a very hard material that has a Wurtzite crystal structure .
A compound semiconductor is a semiconductor compound composed of chemical elements of at least two different species. These semiconductors form for example in periodic table groups 13–15 (old groups III–V), for example of elements from the Boron group (old group III, boron, aluminium, gallium, indium) and from group 15 (old group V, nitrogen, phosphorus, arsenic, antimony, bismuth).
However, they also tend to be more expensive due to smaller wafer sizes and increased material fragility. Silicon germanium (SiGe) is a Si-based compound semiconductor technology offering higher-speed transistors than conventional Si devices but with similar cost advantages. Gallium nitride (GaN) is also an option for MMICs. [1]
There are many III–V and II–VI compound semiconductors with wide bandgaps. In the III-V semiconductor family, aluminium nitride (AlN) is used to fabricate ultraviolet LEDs with wavelengths down to 200–250 nm, gallium nitride (GaN) is used to make blue LEDs and laser diodes, and boron nitride (BN) is proposed for blue LEDs.
A new style of wafers composed of gallium-nitride-on-silicon (GaN-on-Si) is being used to produce white LEDs using 200-mm silicon wafers. This avoids the typical costly sapphire substrate in relatively small 100- or 150-mm wafer sizes. [34]
The semiconductors gallium nitride and indium gallium nitride are used in blue and violet optoelectronic devices, mostly laser diodes and light-emitting diodes. For example, gallium nitride 405 nm diode lasers are used as a violet light source for higher-density Blu-ray Disc compact data disc drives. [74]
Indium gallium nitride (InGaN) is a semiconductor material made of a mix of gallium nitride (GaN) and indium nitride (InN). It is a ternary group III–V direct bandgap semiconductor. Its bandgap can be tuned by varying the amount of indium in the alloy from 0.7 eV to 3.4 eV, thus making it an ideal material for solar cells. [ 35 ]
LED display of a TI-30 scientific calculator (c. 1978), which uses plastic lenses to increase the visible digit size X-Ray of a 1970s 8-digit LED calculator display. Until 1968, visible and infrared LEDs were extremely costly, on the order of US$200 per unit, and so had little practical use. [23]
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