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Sodium sulfate is a typical electrostatically bonded ionic sulfate. The existence of free sulfate ions in solution is indicated by the easy formation of insoluble sulfates when these solutions are treated with Ba 2+ or Pb 2+ salts: Na 2 SO 4 + BaCl 2 → 2 NaCl + BaSO 4. Sodium sulfate is unreactive toward most oxidizing or reducing agents.
The Leblanc process was an early industrial process for making soda ash (sodium carbonate) used throughout the 19th century, named after its inventor, Nicolas Leblanc.It involved two stages: making sodium sulfate from sodium chloride, followed by reacting the sodium sulfate with coal and calcium carbonate to make sodium carbonate.
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The Mannheim process is an industrial process for the production of hydrogen chloride and sodium sulfate from sulfuric acid and sodium chloride. [1] The Mannheim furnace is also used to produce potassium sulfate from potassium chloride. [2] The Mannheim process is a stage in the Leblanc process for the production of sodium carbonate.
By 1791, Nicolas Leblanc had succeeded in producing sodium carbonate from salt by a 2-step process. In the first step, sodium chloride is mixed with concentrated sulfuric acid at temperatures of 800–900 °C; hydrogen chloride gas is evolved, leaving solid sodium sulfate.
The SO 2 is absorbed in the water, and when oxygen is added reacts to form sulfate ions SO 2− 4 and free H +. The surplus of H + is offset by the carbonates in seawater pushing the carbonate equilibrium to release CO 2 gas: SO 2 + H 2 O + O →H 2 SO 4 HCO − 3 + H + → H 2 O + CO 2. In industry caustic soda (NaOH) is often used to scrub SO ...
Sulfation is widely used in the production of consumer products such as detergents, shampoos, and cosmetics. Since the sulfate group is highly polar, its conjugation to a lipophilic "tail" gives surfacant-like properties. Well known sulfates are sodium lauryl sulfate and sodium laureth sulfate. [2]
[11] [12] During combustion, sodium sulfate is reduced to sodium sulfide by the organic carbon in the mixture: 1. Na 2 SO 4 + 2 C → Na 2 S + 2 CO 2. This reaction is similar to thermochemical sulfate reduction in geochemistry. The molten salts ("smelt") from the recovery boiler are dissolved in a process water known as "weak wash".