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Bromoform was discovered in 1832 by Löwig who distilled a mixture of bromal and potassium hydroxide, as analogous to preparation of chloroform from chloral. [5]Bromoform can be prepared by the haloform reaction using acetone and sodium hypobromite, by the electrolysis of potassium bromide in ethanol, or by treating chloroform with aluminium bromide.
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This list is sorted by boiling point of gases in ascending order, but can be sorted on different values. "sub" and "triple" refer to the sublimation point and the triple point, which are given in the case of a substance that sublimes at 1 atm; "dec" refers to decomposition. "~" means approximately.
The EPA limits the total concentration of the four chief constituents (chloroform, bromoform, bromodichloromethane, and dibromochloromethane), referred to as total trihalomethanes (TTHM), to 80 parts per billion in treated water. [6] Traces of chloroform are produced in swimming pools. [7] [8] [9] [10]
Originally, it was simply casing-head gas or drip gas, which has similar properties. Drip gas was sold commercially at gas stations and hardware stores in North America until the early 1950s. The white gas sold today is a similar product but is produced at refineries and has a very low benzene content, benzene being a human carcinogen. [5]
These toxic chemicals are avoided today in consideration of the fact that there are alternative water based, non-toxic heavy liquids like sodium polytungstate solutions. [1] With this relatively new heavy liquid densities up to 3.1 g·cm −3 can be adjusted . Adding parts of pulverulent tungsten carbide increases the density to 4.6 g·cm −3. [2]
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This colorless, odorless, nonflammable gas is produced both industrially and biologically. It is a recognized ozone-depleting chemical. According to the IPCC Fifth Assessment Report, it has a global warming potential of 2. [5] The compound was used extensively as a pesticide until being phased out by most countries in the early 2000s. [6]