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A supersaturated solution of sodium acetate in water is supplied with a device to initiate crystallization, a process that releases substantial heat. Solubility from CRC Handbook. Sodium acetate trihydrate crystals melt at 58–58.4 °C (136.4–137.1 °F), [12] [13] and the liquid sodium acetate dissolves in the released water of crystallization.
The acetate anion, [CH 3 COO] −,(or [C 2 H 3 O 2] −) is one of the carboxylate family. It is the conjugate base of acetic acid. Above a pH of 5.5, acetic acid converts to acetate: [1] CH 3 COOH ⇌ CH 3 COO − + H + Many acetate salts are ionic, indicated by their tendency to dissolve well in water.
It is very difficult to measure pH values of less than two in aqueous solution with a glass electrode, because the Nernst equation breaks down at such low pH values. To determine p K values of less than about 2 or more than about 11 spectrophotometric [ 60 ] [ 61 ] or NMR [ 62 ] [ 63 ] measurements may be used instead of, or combined with, pH ...
Buffer capacity falls to 33% of the maximum value at pH = pK a ± 1, to 10% at pH = pK a ± 1.5 and to 1% at pH = pK a ± 2. For this reason the most useful range is approximately pK a ± 1. When choosing a buffer for use at a specific pH, it should have a pK a value as close as possible to that pH. [2]
For example, the acid may be acetic acid and the salt may be sodium acetate. The Henderson–Hasselbalch equation relates the pH of a solution containing a mixture of the two components to the acid dissociation constant, K a of the acid, and the concentrations of the species in solution. [6]
The equilibrium constant is found by fitting calculated pH values to the observed values, ... Its conjugate base is the acetate ion with K b = 10 −14 /K a = 5.7 x ...
For radiolabeling, the pH of the 68 Ga containing generator eluate has to be raised from its initial value (depending on HCl concentration, pH 1–1.5) to pH 2–3.5 [6] using suitable buffers, such as sodium acetate.
Typically aqueous sodium hydroxide solutions are used. [1] [2] It is an important type of alkaline hydrolysis. When the carboxylate is long chain, its salt is called a soap. The saponification of ethyl acetate gives sodium acetate and ethanol: C 2 H 5 O 2 CCH 3 + NaOH → C 2 H 5 OH + NaO 2 CCH 3