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Pedomicrobium is a ubiquitous bacterium dominant in biofilms of man-made aquatic environments such as water distribution systems and bioreactors. Due to their abilities to oxidise manganese (Mn), they are found to be the main culprits of Mn related “dirty water” (Sly et al., 1988a).
Manganese is a silvery-gray metal that resembles iron. It is hard and very brittle, difficult to fuse, but easy to oxidize. [11] Manganese and its common ions are paramagnetic. [12] Manganese tarnishes slowly in air and oxidizes ("rusts") like iron in water containing dissolved oxygen. [13]
The complex is a cluster containing four manganese and one calcium ions, but the exact location and mechanism of water oxidation within the cluster is unknown. Nevertheless, bio-inspired manganese and manganese-calcium complexes have been synthesized, such as [Mn 4 O 4] cubane-type clusters, some with catalytic activity. [58]
In a large sample of adults of all ages and both sexes, the figure for water fraction by weight was found to be 48 ±6% for females and 58 ±8% water for males. [8] Water is ~11% hydrogen by mass but ~67% hydrogen by atomic percent , and these numbers along with the complementary % numbers for oxygen in water, are the largest contributors to ...
Manganese is also important in photosynthetic oxygen evolution in chloroplasts in plants. The oxygen-evolving complex (OEC) is a part of photosystem II contained in the thylakoid membranes of chloroplasts; it is responsible for the terminal photooxidation of water during the light reactions of photosynthesis , and has a metalloenzyme core ...
The GEOTRACES program has led the production of the first global manganese model, in which predictions of global manganese distribution can be made. [27] This global model found strong removal rates of Mn as water moves from the Atlantic Ocean surface to the North Atlantic deep water resulting in Mn depletion in water moving southward along the ...
The manganese can be recovered by the Weldon process. [11] Small amounts of chlorine gas can be made in the laboratory by putting concentrated hydrochloric acid in a flask with a side arm and rubber tubing attached. Manganese dioxide is then added and the flask stoppered. The reaction is not greatly exothermic.
It is used as a regeneration chemical to remove iron and hydrogen sulfide (rotten egg smell) from well water via a "manganese greensand" filter. "Pot-Perm" is also obtainable at pool supply stores and is used additionally to treat wastewater. Historically it was used to disinfect drinking water [37] [38] and can turn the water pink. [39]