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In 1884, Svante Arrhenius proposed that a base is a substance which dissociates in aqueous solution to form hydroxide ions OH −. These ions can react with hydrogen ions (H + according to Arrhenius) from the dissociation of acids to form water in an acid–base reaction. A base was therefore a metal hydroxide such as NaOH or Ca(OH) 2.
In chemistry, an acid–base reaction is a chemical reaction that occurs between an acid and a base.It can be used to determine pH via titration.Several theoretical frameworks provide alternative conceptions of the reaction mechanisms and their application in solving related problems; these are called the acid–base theories, for example, Brønsted–Lowry acid–base theory.
In physical chemistry, the Arrhenius equation is a formula for the temperature dependence of reaction rates.The equation was proposed by Svante Arrhenius in 1889, based on the work of Dutch chemist Jacobus Henricus van 't Hoff who had noted in 1884 that the van 't Hoff equation for the temperature dependence of equilibrium constants suggests such a formula for the rates of both forward and ...
In the same year that Brønsted and Lowry published their theory, G. N. Lewis created an alternative theory of acid–base reactions. The Lewis theory is based on electronic structure. A Lewis base is a compound that can give an electron pair to a Lewis acid, a compound that can accept an electron pair.
[2] [17] The Brønsted–Lowry acid–base theory was published in the same year. The two theories are distinct but complementary. A Lewis base is also a Brønsted–Lowry base, but a Lewis acid does not need to be a Brønsted–Lowry acid. The classification into hard and soft acids and bases (HSAB theory) followed in 1963.
On the other hand, if a chemical is a weak acid its conjugate base will not necessarily be strong. Consider that ethanoate, the conjugate base of ethanoic acid, has a base splitting constant (Kb) of about 5.6 × 10 −10, making it a weak base. In order for a species to have a strong conjugate base it has to be a very weak acid, like water.
Arrhenius may refer to: Birgit Arrhenius (born 1932), Swedish archaeologist Carl Axel Arrhenius (1757–1824), Swedish army lieutenant and amateur mineralogist who discovered ytterbite , a mineral that led to the discovery of yttrium by Johan Gadolin
The following outline acts as an overview of and topical guide to chemistry: . Chemistry is the science of atomic matter (matter that is composed of chemical elements), especially its chemical reactions, but also including its properties, structure, composition, behavior, and changes as they relate to the chemical reactions.