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The soil's pH also has a strong effect on the amount of volatilization. Specifically, highly alkaline soils (pH~8.2 or higher) have proven to increase urea hydrolysis. One study has shown complete hydrolysis of urea within two days of application on such soils. In acidic soils (pH 5.2) the urea took twice as long to hydrolyze. [7]
Polymer-coated urea, also called plastic-coated urea, or PCU, fertilizers can permit a more precise rate of nitrogen release than sulfur-coated urea products. It's possible to produce polymer-coated products where the nitrogen release can be delayed for 10 months after application.
For fertilizer use, granules are preferred over prills because of their narrower particle size distribution, which is an advantage for mechanical application. Urea is usually spread at rates of between 40 and 300 kg/ha (35 to 270 lbs/acre) but rates vary. Smaller applications incur lower losses due to leaching.
Use the 4 Rs to help keep nutrients and fertilizer in the soil.
Controlled release fertilizers are traditional fertilizers encapsulated in a shell that degrades at a specified rate. Sulfur is a typical encapsulation material. Other coated products use thermoplastics (and sometimes ethylene-vinyl acetate and surfactants, etc.) to produce diffusion-controlled release of urea or other fertilizers. "Reactive ...
The combination of urea and ammonium nitrate has an extremely low critical relative humidity (18% at 30 °C) and can therefore only be used in liquid fertilizers. The most commonly used grade of these fertilizer solutions is UAN 32.0.0 (32%N) known as UN32 or UN-32, which consists of 45% ammonium nitrate , 35% urea and only 20% water.
Crops do not always require a uniform application, as some areas will have different nutrient requirements due to their location (soil properties, sunlight). [2] Variable rate fertilizer spreaders can be used to increase or decrease fertilizer application rate, using a global positioning system (GPS). [5]
The structure of the molecule of urea is O=C(−NH 2) 2.The urea molecule is planar when in a solid crystal because of sp 2 hybridization of the N orbitals. [8] [9] It is non-planar with C 2 symmetry when in the gas phase [10] or in aqueous solution, [9] with C–N–H and H–N–H bond angles that are intermediate between the trigonal planar angle of 120° and the tetrahedral angle of 109.5°.
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