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  2. Chemical bonding of water - Wikipedia

    en.wikipedia.org/wiki/Chemical_bonding_of_water

    2 O is sp 3 hybridized in which the 2s atomic orbital and the three 2p orbitals of oxygen are hybridized to form four new hybridized orbitals which then participate in bonding by overlapping with the hydrogen 1s orbitals. As such, the predicted shape and bond angle of sp 3 hybridization is tetrahedral and 109.5°. This is in open agreement with ...

  3. Bent's rule - Wikipedia

    en.wikipedia.org/wiki/Bent's_rule

    Shape of water molecule showing that the real bond angle 104.5° deviates from the ideal sp 3 angle of 109.5°. In chemistry, Bent's rule describes and explains the relationship between the orbital hybridization and the electronegativities of substituents. [1] [2] The rule was stated by Henry A. Bent as follows: [2]

  4. Orbital hybridisation - Wikipedia

    en.wikipedia.org/wiki/Orbital_hybridisation

    In chemistry, orbital hybridisation (or hybridization) is the concept of mixing atomic orbitals to form new hybrid orbitals (with different energies, shapes, etc., than the component atomic orbitals) suitable for the pairing of electrons to form chemical bonds in valence bond theory.

  5. Isovalent hybridization - Wikipedia

    en.wikipedia.org/wiki/Isovalent_hybridization

    In chemistry, isovalent or second order hybridization is an extension of orbital hybridization, the mixing of atomic orbitals into hybrid orbitals which can form chemical bonds, to include fractional numbers of atomic orbitals of each type (s, p, d). It allows for a quantitative depiction of bond formation when the molecular geometry deviates ...

  6. Homolysis (chemistry) - Wikipedia

    en.wikipedia.org/wiki/Homolysis_(chemistry)

    An sp3 hybridized atom is the most stable configuration for a radical because of the low s-character. Orbital hybridization. The s-character of an orbital relates to how close electrons are to the nucleus. In the case of a radical, s-character more specifically relates to how close the single electron is to the nucleus.

  7. Hydronium - Wikipedia

    en.wikipedia.org/wiki/Hydronium

    In chemistry, hydronium (hydroxonium in traditional British English) is the cation [H 3 O] +, also written as H 3 O +, the type of oxonium ion produced by protonation of water.It is often viewed as the positive ion present when an Arrhenius acid is dissolved in water, as Arrhenius acid molecules in solution give up a proton (a positive hydrogen ion, H +) to the surrounding water molecules (H 2 O).

  8. Oxonium ion - Wikipedia

    en.wikipedia.org/wiki/Oxonium_ion

    Oxygen is usually pyramidal with an sp 3 hybridization. Those with n = 1 are called primary oxonium ions, an example being protonated alcohol (e.g. methanol). In acidic media, the oxonium functional group produced by protonating an alcohol can be a leaving group in the E2 elimination reaction. The product is an alkene. Extreme acidity, heat ...

  9. Self-ionization of water - Wikipedia

    en.wikipedia.org/wiki/Self-ionization_of_water

    A solution in which the H 3 O + and OH − concentrations equal each other is considered a neutral solution. In general, the pH of the neutral point is numerically equal to ⁠ 1 / 2 ⁠ pK w. Pure water is neutral, but most water samples contain impurities. If an impurity is an acid or base, this will affect the concentrations of hydronium ion ...

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