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A carbonate is a salt of carbonic acid, (H 2 CO 3), [2] characterized by the presence of the carbonate ion, a polyatomic ion with the formula CO 2− 3. The word "carbonate" may also refer to a carbonate ester , an organic compound containing the carbonate group O=C(−O−) 2 .
The bicarbonate ion carries a negative one formal charge and is an amphiprotic species which has both acidic and basic properties. It is both the conjugate base of carbonic acid H 2 CO 3; and the conjugate acid of CO 2− 3, the carbonate ion, as shown by these equilibrium reactions: CO 2− 3 + 2 H 2 O ⇌ HCO − 3 + H 2 O + OH − ⇌ H 2 CO ...
The name of the cation (the unmodified element name for monatomic cations) comes first, followed by the name of the anion. [100] [101] For example, MgCl 2 is named magnesium chloride, and Na 2 SO 4 is named sodium sulfate (SO 2− 4, sulfate, is an example of a polyatomic ion).
Elements of the first row are limited to a maximum coordination number of 4. However, none of the first row elements has a monomeric oxyanion with that coordination number. Instead, carbonate (CO 2− 3) and nitrate (NO − 3) have a trigonal planar structure with π bonding between the central atom and the oxygen atoms. This π bonding is ...
For cations that take on multiple charges, the charge is written using Roman numerals in parentheses immediately following the element name. For example, Cu(NO 3) 2 is copper(II) nitrate, because the charge of two nitrate ions (NO − 3) is 2 × −1 = −2, and since the net charge of the ionic compound must be zero, the Cu ion has a 2+ charge ...
The formal charge of an atom is computed as the difference between the number of valence electrons that a neutral atom would have and the number of electrons that belong to it in the Lewis structure. Electrons in covalent bonds are split equally between the atoms involved in the bond.
To a single metal ion, carbonate is observed to bind in both unidentate (κ 1-) and bidentate (κ 2-) fashions. [5] In the covalent bond classification method, κ 1-carbonate is anX ligand and κ 2-carbonate is an X 2 ligand. With two metals, the number of bonding modes increases because carbonate often serves as a bridging ligand.
Carbon trioxide should not be confused with the stable carbonate ion (CO 2− 3). Carbon trioxide can be produced, for example, in the drift zone of a negative corona discharge by reactions between carbon dioxide (CO 2) and the atomic oxygen (O) created from molecular oxygen by free electrons in the plasma. [2]