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  2. Bjerrum plot - Wikipedia

    en.wikipedia.org/wiki/Bjerrum_plot

    At any equilibrium, the concentrations are unchanging, hence the left hand sides of these equations are zero. Then, from the first of these four equations, the ratio of reaction 1 ' s rate constants equals the ratio of its equilibrium concentrations, and this ratio, called K 1 , is called the equilibrium constant for reaction 1 , i.e.

  3. Van 't Hoff equation - Wikipedia

    en.wikipedia.org/wiki/Van_'t_Hoff_equation

    For a reversible reaction, the equilibrium constant can be measured at a variety of temperatures. This data can be plotted on a graph with ln K eq on the y-axis and ⁠ 1 / T ⁠ on the x axis. The data should have a linear relationship, the equation for which can be found by fitting the data using the linear form of the Van 't Hoff equation

  4. Chemical equilibrium - Wikipedia

    en.wikipedia.org/wiki/Chemical_equilibrium

    For example, in the case of acetic acid dissolved in water and forming acetate and hydronium ions, CH 3 CO 2 H + H 2 O ⇌ CH 3 CO − 2 + H 3 O + a proton may hop from one molecule of acetic acid onto a water molecule and then onto an acetate anion to form another molecule of acetic acid and leaving the number of acetic acid molecules unchanged.

  5. Equilibrium chemistry - Wikipedia

    en.wikipedia.org/wiki/Equilibrium_chemistry

    as this shows that when hydrogen ion concentration increases the equilibrium is shifted to the left in accordance with Le Châtelier's principle. Hydrogen ion concentration can be increased by the presence of carbon dioxide, which behaves as a weak acid. H 2 O + CO 2 ⇌ HCO − 3 + H + The iron atom can also bind to other molecules such as ...

  6. Azeotrope tables - Wikipedia

    en.wikipedia.org/wiki/Azeotrope_tables

    This page contains tables of azeotrope data for various binary and ternary mixtures of solvents. The data include the composition of a mixture by weight (in binary azeotropes, when only one fraction is given, it is the fraction of the second component), the boiling point (b.p.) of a component, the boiling point of a mixture, and the specific gravity of the mixture.

  7. Electrolysis of water - Wikipedia

    en.wikipedia.org/wiki/Electrolysis_of_water

    Pure water has a charge carrier density similar to semiconductors [12] [page needed] since it has a low autoionization, K w = 1.0×10 −14 at room temperature and thus pure water conducts current poorly, 0.055 μS/cm. [13] Unless a large potential is applied to increase the autoionization of water, electrolysis of pure water proceeds slowly ...

  8. Equilibrium constant - Wikipedia

    en.wikipedia.org/wiki/Equilibrium_constant

    The deuterated acid is studied in heavy water, since if it were dissolved in ordinary water the deuterium would rapidly exchange with hydrogen in the solvent. [ 19 ] The product species H 3 O + (or D 3 O + ) is a stronger acid than the solute acid, so that it dissociates more easily, and its H–O (or D–O) bond is weaker than the H–A (or D ...

  9. Self-ionization of water - Wikipedia

    en.wikipedia.org/wiki/Self-ionization_of_water

    The self-ionization of water (also autoionization of water, autoprotolysis of water, autodissociation of water, or simply dissociation of water) is an ionization reaction in pure water or in an aqueous solution, in which a water molecule, H 2 O, deprotonates (loses the nucleus of one of its hydrogen atoms) to become a hydroxide ion, OH −. The ...